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Merck
CN

931845

GenOx-PJ

别名:

3-Oxo-2-tosyl-2,3-dihydro-1H-1λ3-benzo[d][1,2]iodazol-1-yl acetate

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关于此项目

经验公式(希尔记法):
C16H14INO5S
化学文摘社编号:
分子量:
459.26
MDL number:
NACRES:
NA.21
UNSPSC Code:
12352200
Form:
powder
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form

powder

Quality Segment

mp

>300 °C

functional group

iodo

storage temp.

−20°C

Application

GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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