931845
GenOx-PJ
Synonym(s):
3-Oxo-2-tosyl-2,3-dihydro-1H-1λ3-benzo[d][1,2]iodazol-1-yl acetate
Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Empirical Formula (Hill Notation):
C16H14INO5S
CAS Number:
Molecular Weight:
459.26
MDL number:
NACRES:
NA.21
UNSPSC Code:
12352200
Form:
powder
Application
GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon?Oxygen Bond Formation
Li P, et al.
ACS Catalysis, 11(17), 10997?11004-10997?11004 (2021)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 931845-2G | 04065269116059 |
| 931845-500MG | 04065269116066 |