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Merck
CN

936154

RUPipIPr

greener alternative

≥95%, powder

Synonym(s):

2-(2,6-Diisopropylphenyl)-5-(piperidin-1-yl)-2H-imidazo[1,5-a]pyridin-4-ium chloride

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About This Item

Empirical Formula (Hill Notation):
C24H32ClN3
CAS Number:
2946617-42-9
Molecular Weight:
397.98
UNSPSC Code:
12161600
NACRES:
NA.22

Key Documents

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Product Name

RUPipIPr, ≥95%

InChI

1S/C24H32N3.ClH/c1-18(2)21-11-9-12-22(19(3)4)24(21)26-16-20-10-8-13-23(27(20)17-26)25-14-6-5-7-15-25;/h8-13,16-19H,5-7,14-15H2,1-4H3;1H/q+1;/p-1

InChI key

QJSWQOLTDTUXIQ-UHFFFAOYSA-M

SMILES string

CC(C1=CC=CC(C(C)C)=C1N2C=[N+]3C(C=CC=C3N4CCCCC4)=C2)C.[Cl-]

assay

≥95%

form

powder

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

greener alternative category

Aligned

Quality Level

100

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

RUPipIPr is a NHC ligand developed by the Szostak Group. This NHC analogue of the priviledged DalPhos scaffold has been used in the following reactions: Au-catalyzed C-C coupling, Au-catalyzed C-N coupling, and Au-catalyzed hydroamination of internal alkynes.

Other Notes

L-Shaped Heterobidentate Imidazo[1,5-a]pyridin-3-ylidene (N,C)-Ligands for Oxidant-Free AuI/AuIII Catalysis

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
0000305156
0000305156
0000284865
0000284865

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