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Merck
CN

936162

RUMeIPr*

greener alternative

≥95%, powder

Synonym(s):

2-(2,6-Dibenzhydryl-4-methylphenyl)-5-(dimethylamino)-2H-imidazo[1,5-a]pyridin-4-ium chloride

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About This Item

Empirical Formula (Hill Notation):
C42H38ClN3
CAS Number:
2820157-09-1
Molecular Weight:
620.22
UNSPSC Code:
12161600
NACRES:
NA.22

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Product Name

RUMeIPr*, ≥95%

InChI

1S/C42H38N3.ClH/c1-31-27-37(40(32-17-8-4-9-18-32)33-19-10-5-11-20-33)42(44-29-36-25-16-26-39(43(2)3)45(36)30-44)38(28-31)41(34-21-12-6-13-22-34)35-23-14-7-15-24-35;/h4-30,40-41H,1-3H3;1H/q+1;/p-1

InChI key

PHYDGCNSIQWIAX-UHFFFAOYSA-M

SMILES string

CN(C)C1=CC=CC2=CN(C3=C(C(C4=CC=CC=C4)C5=CC=CC=C5)C=C(C)C=C3C(C6=CC=CC=C6)C7=CC=CC=C7)C=[N+]21.[Cl-]

assay

≥95%

form

powder

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

greener alternative category

Aligned

Quality Level

100

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

RUMeIPr* is a NHC ligand developed by the Szostak Group. This NHC analogue of the priveledged DalPhos scaffold has been used in the following reactions: Au-catalyzed C-C coupling, Au-catalyzed C-N coupling, and Au-catalyzed hydroamination of internal alkynes.

Other Notes

L-Shaped Heterobidentate Imidazo1,5-ajpyridin-3-ylidene (NC)-Ligands for Oxidant-Free Aul/AullI Catalysis

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
0000302505
0000302505
0000282710
0000282710

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