937371
(AdBrettPhos)Pd(p-CH3C6H4(OTf)
powder or crystals
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About This Item
Empirical Formula (Hill Notation):
C51H68F3O5PPdS
CAS Number:
Molecular Weight:
987.54
NACRES:
NA.21
Form:
powder or crystals
Product Name
(AdBrettPhos)Pd(p-CH3C6H4(OTf),
SMILES string
CC(C=C1)=CC=C1[Pd](OS(=O)(C(F)(F)F)=O)[P](C2=C(OC)C=CC(OC)=C2C3=C(C(C)C)C=C(C(C)C)C=C3C(C)C)(C45C[C@H]6C[C@H](C[C@H](C6)C5)C4)C78C[C@H]9C[C@H](C[C@H](C9)C8)C7
form
powder or crystals
reaction suitability
reaction type: Cross Couplings
color
white to dark yellow, dark beige
functional group
(Palladium), phosphine
Quality Level
General description
(AdBrettPhos)Pd(p-CH3C6H4)(OTf) is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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