Lithium nickel manganese cobalt oxide

Lithium niobate coated NMC622 is a powdered form of lithium nickel manganese cobalt oxide with a stoichiometry of 6:2:2 Ni:Mn:Co and a typical particle size of 4-10 microns. The particles are coated in 5-10 nm amorphous lithium niobate, less than 1 wt.%.

LiNbO₃-coated NMC622 is a high-performance cathode active material specially designed for lithium-ion batteries (LIBs), particularly solid-state and high-voltage batteries. With a balance of 60% nickel for high capacity and 40% manganese and cobalt for structural stability, NMC622 surpasses NMC811 in terms of cycling lifetime and coulombic efficiencies and offers higher capacity than NMC532. The LiNbO₃ coating plays a vital role in enhancing the stability of the cathode material by safeguarding the electrode and electrolyte from undesired reactions. Research suggests that this lithium-niobate coating mitigates reactions between the cathode material and electrolyte, reducing capacity fade over time and impeding the release of metal ions from the NMC cathode. Additionally, the LiNbO₃ “insertion layer” improves rate capability by minimizing the space charge layer barrier at the electrolyte/cathode interface. This advancement translates to superior Li diffusion and reduced electrode polarization.

•NMC622: High capacity and long cycle lifetimes
•LiNbO₃ coating: Enhanced protection for cathode and electrolyte, leading to improved coulombic efficiency
•LiNbO₃ insertion layer: Boosts rate capability