940984
N-(2,6-Dimethylphenyl)-6-hydroxypicolinamide
>95%
Synonym(s):
6-Hydroxy picolinohydrazide, N-(2,6-Dimethylphenyl)-6-oxo-1H-pyridine-2-carboxamide, MPBS
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About This Item
Empirical Formula (Hill Notation):
C14H14N2O2
CAS Number:
Molecular Weight:
242.27
MDL number:
NACRES:
NA.21
Assay:
>95%
Form:
powder
SMILES string
O=C1C=CC=C(N1)C(=O)NC=2C(=CC=CC2C)C
InChI key
RLTMFMKUMLGROY-UHFFFAOYSA-N
InChI
InChI=1S/C14H14N2O2/c1-9-5-3-6-10(2)13(9)16-14(18)11-7-4-8-12(17)15-11/h3-8H,1-2H3,(H,15,17)(H,16,18)
assay
>95%
form
powder
color
white to off-white
Quality Level
General description
N-(2,6-Dimethylphenyl)-6-hydroxypicolinamide is a picolinamide ligand commonly used in copper catalyzed reactions.
Application
The ligand has been used in:
- The Cu-catalyzed sulfonamidation of (hetero)aryl halides
- The Cu-catalyzed cross coupling of primary amines and (hetero)aryl bromides
- Cu-catalyzed hydroxylation reactions of (hetero)aryl halides in water
- The synthesis of biaryl amines via the coupling of anilines and (hetero)aryl halides
Features and Benefits
Picolinamide ligands are useful in a range of Cu catalyzed cross coupling reactions. Such reactions often offer advantages over conventional palladium or Nickel catalyzed cross coupling reactions, such as:
- Lower metal costs
- Lower metal toxicity
- Better substrate scope
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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