ALD00006
Sodium bis(2-hydroxy-2-methylbutyrato)oxochromate(V)
Synonym(s):
2-Hydroxy-2-methyl-butanoic acid chromium complex
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About This Item
Empirical Formula (Hill Notation):
C10H16CrNaO7
CAS Number:
Molecular Weight:
323.22
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
form
solid
Quality Level
mp
340-350 °C
SMILES string
[O-][Cr]1(O2)(OC(C(C)(CC)O1)=O)OC(C)(CC)C2=O.[Na+]
InChI
1S/2C5H9O3.Cr.Na.O/c2*1-3-5(2,8)4(6)7;;;/h2*3H2,1-2H3,(H,6,7);;;/q2*-1;+4;+1;-1/p-2
InChI key
NIZKSTMLMALTGU-UHFFFAOYSA-L
Application
Oxidant was reported by the Baran group to promote selective allylic oxidation of a synthetic intermediate derived from (+)-taxadiene en route to the synthesis of (−)-taxyunnanine D.
Two-Phase Synthesis of (−)-Taxuyunnanine D
Two-Phase Synthesis of (−)-Taxuyunnanine D
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