ALD00616
Ethyl (R,E)-2-((mesitylsulfinyl)imino)acetate
≥95%
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About This Item
Empirical Formula (Hill Notation):
C13H17NO3S
CAS Number:
Molecular Weight:
267.34
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22
Assay:
≥95%
Form:
powder
InChI key
OUMNTVUUJPMNPJ-RIYZIHGNSA-N
InChI
1S/C13H17NO3S/c1-5-17-12(15)8-14-18(16)13-10(3)6-9(2)7-11(13)4/h6-8H,5H2,1-4H3/b14-8+
SMILES string
[S](=O)(\N=C\C(=O)OCC)c1c(cc(cc1C)C)C
assay
≥95%
form
powder
reaction suitability
reaction type: C-C Bond Formation
mp
62-65 °C
storage temp.
−20°C
Quality Level
Related Categories
Application
Ethyl (R,E)-2-((mesitylsulfinyl)imino)acetate is a chiral glyoxylate-derived sulfinimine reagent used for the synthesis of optically pure amino acids through a decarboxylative radical cross-coupling reaction.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Shengyang Ni et al.
Angewandte Chemie (International ed. in English), 57(44), 14560-14565 (2018-09-14)
The direct union of primary, secondary, and tertiary carboxylic acids with a chiral glyoxylate-derived sulfinimine provides rapid access into a variety of enantiomerically pure α-amino acids (>85 examples). Characterized by operational simplicity, this radical-based reaction enables the modular assembly of
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