C11081
Tetrabromomethane
ReagentPlus®, 99%
Synonym(s):
Carbon tetrabromide
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About This Item
Empirical Formula (Hill Notation):
CBr4
CAS Number:
Molecular Weight:
331.63
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-189-6
Beilstein/REAXYS Number:
1732799
MDL number:
Assay:
99%
Form:
crystals
InChI key
HJUGFYREWKUQJT-UHFFFAOYSA-N
InChI
1S/CBr4/c2-1(3,4)5
SMILES string
BrC(Br)(Br)Br
vapor pressure
40 mmHg ( 96 °C)
product line
ReagentPlus®
assay
99%
form
crystals
Quality Level
Related Categories
General description
Tetrabromomethane can serve as a mediator, catalyst, and reagent in the synthesis of valuable chemicals.
Application
Tetrabromomethane may be used in the following applications:
- As a transfer agent for the copolymerization of methylmethacrylate and p-divinylbenzene to form soluble crosslinked polymers.
- As a catalyst for the aerobic photooxidative synthesis of aromatic esters from benzyl alcohols under metal-free conditions.
- Bromination of adamantane and its derivatives in the presence of iron compounds as catalyst.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Bromination of adamantane and its derivatives with tetrabromomethane catalyzed by iron compounds.
Khusnutdinov RI
Russ. J. Org. Chem., 51(2), 184-187 (2015)
Aerobic oxidative esterification of benzyl alcohols with catalytic tetrabromomethane under visible light irradiation.
Nobuta T
Tetrahedron Letters, 53(39), 5306-5308 (2012)
Preparation of soluble microgel by the copolymerization of methylmethacrylate with p?divinylbenzene in the presence of tetrabromomethane.
Chen H
Journal of Polymer Science Part A: Polymer Chemistry, 22(9), 2123-2130 (1984)
Recent advances in the application of tetrabromomethane in organic synthesis
Kumar S, et al.
Inorganic chemistry frontiers, 8(15), 4288-4314 (2021)
A K Agarwal et al.
Toxicology letters, 17(1-2), 57-62 (1983-06-01)
The hepatotoxic and nephrotoxic effects of CBr4 were studied in male Sprague-Dawley rats following a single i.p. administration in a dose range of 25 to 125 microliter/kg to animals maintained for 15 days either on normal diet or a diet
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