CF0017
Imidazolyltetrafluorobromoethane
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About This Item
Linear Formula:
C5H3BrF4N2
CAS Number:
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Form:
liquid
SMILES string
FC(F)(Br)C(F)(F)[n]1cncc1
InChI
1S/C5H3BrF4N2/c6-4(7,8)5(9,10)12-2-1-11-3-12/h1-3H
InChI key
WHWVFYIPMIWMMK-UHFFFAOYSA-N
form
liquid
reaction suitability
reaction type: C-C Bond Formation
Related Categories
Application
Imidazolyltetrafluorobromoethane is a fluoroalkylbromide that is a radical source of the imidazolyltetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines.
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Legal Information
Product of CF Plus Chemicals.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Articles
Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.
目前的氟烷基化工具包括Togni试剂、高价碘全氟烷基化试剂、氟烷基溴化物、硅烷类和羧酸盐类以及用于后期氟烷基化的磺酰氟类。
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