H11602
Hexamethylphosphoramide
99%
Synonym(s):
HMPA, Hexamethylphosphoric acid triamide, Tris(dimethylamino)phosphine oxide
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About This Item
Linear Formula:
[(CH3)2N]3PO
CAS Number:
Molecular Weight:
179.20
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-653-8
Beilstein/REAXYS Number:
1099903
MDL number:
Assay:
99%
vapor density
6.18 (vs air)
Quality Level
vapor pressure
0.07 mmHg ( 25 °C)
assay
99%
refractive index
n20/D 1.459 (lit.)
bp
230-232 °C/740 mmHg (lit.)
mp
7 °C (lit.)
density
1.03 g/mL at 25 °C (lit.)
SMILES string
CN(C)P(=O)(N(C)C)N(C)C
InChI
1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3
InChI key
GNOIPBMMFNIUFM-UHFFFAOYSA-N
General description
Hexamethylphosphoramide is a polar aprotic solvent.
Application
Hexamethylphosphoramide can be used as a solvent:
- For the conversion of carboxylate salt into esters by reacting with alkyl halides.
- To synthesize aryl thioethers via nucleophilic displacement of unactivated aryl halides by thiolate ions.
- To synthesize polyazomethines (PAZs) from dialdehyde and diamine via high-temperature solution polycondensation.
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signalword
Danger
hcodes
Hazard Classifications
Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
291.2 °F - closed cup
flash_point_c
144 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Hexamethylphosphoramide
Normant H.
Angewandte Chemie (International Edition in English), 6(12), 1046-1067 (1967)
Controlled/?Living? Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate.
Chen X P, et al.
Macromolecules, 35(11), 4277-4281 (2002)
Optical and structural study of thin film of polyazomethine with triphenylamine unit prepared via spin-coating method.
Palewicz M, et al.
Polymer Bull., 66(1), 65-76 (2011)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| H11602-500G | 04061838255945 |
| H11602-100G | 04061833664094 |
| H11602-2.5KG | 04061833664124 |
| H11602-5G | 04061833664131 |