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Merck
CN

360589-M

四氢呋喃

≥99.0%, ACS reagent, contains 250 ppm BHT as inhibitor

别名:

丁烯氧化物, 四亚甲基氧化物, 氧杂环戊烷

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关于此项目

线性分子式:
(CH2)3CH2O
化学文摘社编号:
分子量:
72.11
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12191501
EC Number:
203-726-8
MDL number:
Beilstein/REAXYS Number:
102391
Assay:
≥99.0%
Grade:
ACS reagent
Bp:
65-67 °C (lit.)
Vapor pressure:
114 mmHg ( 15 °C), 143 mmHg ( 20 °C)
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产品名称

四氢呋喃, contains 250 ppm BHT as inhibitor, ACS reagent, ≥99.0%

grade

ACS reagent

vapor density

2.5 (vs air)

vapor pressure

114 mmHg ( 15 °C), 143 mmHg ( 20 °C)

assay

≥99.0%

autoignition temp.

610 °F

contains

250 ppm BHT as inhibitor

expl. lim.

1.8-11.8 %

dilution

(for analytical testing)

impurities

≤0.015% peroxide (as H2O2), ≤0.05% water

evapn. residue

≤0.03%

color

APHA: ≤20

refractive index

n20/D 1.407 (lit.)

bp

65-67 °C (lit.)

mp

−108 °C (lit.)

solubility

water: soluble

density

0.889 g/mL at 25 °C (lit.)

SMILES string

C1CCOC1

InChI

1S/C4H8O/c1-2-4-5-3-1/h1-4H2

InChI key

WYURNTSHIVDZCO-UHFFFAOYSA-N

General description

Tetrahydrofuran (THF) is a widely used organic solvent. On long term storage it forms organic peroxides. This process can be suppressed by adding butylated hydroxytoluene (BHT) as a stabilizer. BHT removes the free radicals required for the peroxide formation. The effect of THF on the biological systems has been studied.

Application

Tetrahydrofuran (THF) was used as a solvent in the following processes:
  • RAFT (Reversible Addition-Fragmentation chain Transfer) polymerization of p-acetoxystyrene.
  • Synthesis of di-tert-butyl-phosphinoferrocene.
  • Synthesis of n-TiO2-based amphiphilic polymer brushes.
  • To dissolve the LiCl from the Mg2Si nanoparticles.
It may be used in the following studies:
  • As an O-donor ligand to form coordination complexes.
  • As mobile phase solvent in high-performance liquid chromatography.
  • As a solvent in the preparation of spin-coated poly(bisphenol A decane ether).
  • Synthesis of THF doped hydrogen clathrate hydrates.

Other Notes

Important notice
This product will be phased out towards early 2019. There is a replacement product available : 360589


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Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

signalword

Danger

supp_hazards

存储类别

3 - Flammable liquids

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.00 °C - closed cup



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