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Merck
CN

31658

Rimsulfuron

PESTANAL®, analytical standard

Synonym(s):

1-(4,6-Dimethoxy-2-pyrimidinyl)-3-[3-(ethylsulfonyl)-2-pyridylsulfonyl]urea

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About This Item

Empirical Formula (Hill Notation):
C14H17N5O7S2
CAS Number:
Molecular Weight:
431.44
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7501778
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grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CCS(=O)(=O)c1cccnc1S(=O)(=O)NC(=O)Nc2nc(OC)cc(OC)n2

InChI

1S/C14H17N5O7S2/c1-4-27(21,22)9-6-5-7-15-12(9)28(23,24)19-14(20)18-13-16-10(25-2)8-11(17-13)26-3/h5-8H,4H2,1-3H3,(H2,16,17,18,19,20)

InChI key

MEFOUWRMVYJCQC-UHFFFAOYSA-N

General description

Rimsulfuron is a sulfonylurea herbicide primarily used to control a wide variety of perennial and annual grasses and some broadleaf weeds. The mode of action of rimsulfuron involves inhibition of acetolactate synthase (ALS), a key enzyme in the biosynthetic pathway of branched-chain amino acids.

Application

Rimsulfuron may be used as a reference standard for the determination of the analyte:
  • In honey samples using a method based on an on-column liquid-liquid extraction (OCLLE) using diatomaceous earth as inert solid support and liquid chromatography (LC) coupled to mass spectrometry (MS) operating in tandem mode (MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany


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Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

农药列管产品

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Paola Ganugi et al.
Plant science : an international journal of experimental plant biology, 303, 110727-110727 (2021-01-26)
Herbicide application is a common procedure in agriculture, whose potentially adverse effects are assessed mainly with respect to weeds or in terms of residues and environmental impact. However, recent evidence has highlighted possible effects of pesticide treatments on plant metabolism
Basis of selectivity of the herbicide rimsulfuron in maize.
Koeppe MK, et al.
Pesticide Biochemistry and Physiology, 66(3), 170- 181 (2000)
Development and validation of a multi-residue method for pesticide determination in honey using on-column liquid- liquid extraction and liquid chromatography- tandem mass spectrometry.
Pirard C, et al.
Journal of Chromatography A, 1152(1-2), 116- 123 (2007)



Global Trade Item Number

SKUGTIN
31658-100MG04061826691021