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Merck
CN

72240

Aluminum-nickel alloy

50% Al basis, 50% Ni basis, powder, purum,

Synonym(s):

Nickel-aluminum alloy, Raney®-Nickel alloy

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About This Item

CAS Number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Aluminum-nickel alloy, purum, 50% Al basis, 50% Ni basis

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

grade

purum

form

powder

composition

Al, 50% , Ni, 50%

reaction suitability

core: nickel, reagent type: catalyst

Quality Level

Application

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.
  • For the conversion of carbonyl compounds to hydrocarbons.
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.
  • For the synthesis of alloyed skeletal Ni catalysts.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

signalword

Danger

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react. 2

Regulatory Information

危险化学品
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Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)

Articles

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

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