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PHR1205

Tributyl phosphate

Pharmaceutical Secondary Standard; Certified Reference Material

Synonym(s):

Tributyl phosphate, TBP, TBPA

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About This Item

Linear Formula:
(CH3(CH2)3O)3PO
CAS Number:
126-73-8
Molecular Weight:
266.31
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329823212
EC Number:
204-800-2
Beilstein/REAXYS Number:
1710584
MDL number:
MFCD00009436

Key Documents

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Product Name

Tributyl phosphate, Pharmaceutical Secondary Standard; Certified Reference Material

InChI

1S/C12H27O4P/c1-4-7-10-14-17(13,15-11-8-5-2)16-12-9-6-3/h4-12H2,1-3H3

InChI key

STCOOQWBFONSKY-UHFFFAOYSA-N

SMILES string

CCCCOP(=O)(OCCCC)OCCCC

grade

certified reference material
pharmaceutical secondary standard

agency

traceable to Ph. Eur. Y0000279

vapor density

9.2 (vs air)

vapor pressure

27 mmHg ( 178 °C)
7.3 mmHg ( 150 °C)

API family

tributyl phosphate

CofA

current certificate can be downloaded

autoignition temp.

770 °F

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.424 (lit.)

bp

180-183 °C/22 mmHg (lit.)

mp

−79 °C (lit.)

density

0.979 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
food and beverages
personal care
pharmaceutical (small molecule)

format

neat

storage temp.

2-30°C

Quality Level

300

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Analysis Note

These secondary standards offer multi-traceability to the US and EP primary standards, where they are available.

Application

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.

General description

Tributyl phosphate is an industrial chemical, commonly used as a plasticizer and a solvent for the extraction of uranium and plutonium in nuclear industry.
Certified pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to in-house working standards.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Ion Mobility: TWCCSN2 value of 164.9 Å2 [M+H]+ and 182.2 Å2 [M+Na]+

The collision cross section (CCS) measurement was provided by Waters Corporation, using the SYNAPT XS mass spectrometer.
For a description and overview of how ion mobility enables the measurement of the CCS of an ion visit ims.waters.com.
Further information on the SYNAPT XS mass spectrometer can be found on the IMS microsite and product webpage.

TWCCS measurements are expected to be within 2% of this reference value.

P/N PHR1205 is part of the Waters Extractables & Leachables UNIFI scientific library which can be downloaded from Waters Marketplace.
This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.
To see an example of a Certificate of Analysis for this material enter P500205 in the slot below. This is an example certificate only and may not be the lot that you receive.

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

293.0 °F - closed cup

flash_point_c

145 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Improved determination of tributyl phosphate degradation products (mono-and dibutyl phosphates) by ion chromatography
Dodi A and Verda G
Journal of Chromatography A, 920(1-2), 275-281 (2001)
T Burnouf et al.
Vox sanguinis, 104(1), 1-6 (2012-07-05)
A minipool solvent/detergent (S/D; 1% TnBP/1% Triton X-45; 31°C) process was developed for viral inactivation of plasma and cryoprecipitate used for transfusion. The goal of this study was to determine the rate and extent of inactivation of dengue virus (DENV)
Domenico Santoro et al.
Environmental science & technology, 44(16), 6233-6241 (2010-08-14)
Advanced Oxidation Processes (AOPs) promoted by ultraviolet light are innovative and potentially cost-effective solutions for treating persistent pollutants recalcitrant to conventional water and wastewater treatment. While several studies have been performed during the past decade to improve the fundamental understanding
Muniasamy Neerathilingam et al.
Toxicology letters, 199(1), 10-16 (2010-08-07)
Tributyl phosphate (TBP) is a toxic organophosphorous compound widely used in many industrial applications, including significant usage in nuclear processing. The industrial application of this chemical is responsible for occupational exposure and environmental pollution. In this study, (1)H NMR-based metabonomics
C W Van Neste et al.
Analytical chemistry, 81(5), 1952-1956 (2009-02-04)
Despite its immediate applications, selective detection of trace quantities of surface adsorbed chemicals, such as explosives, without physically collecting the sample molecules is a challenging task. Standoff spectroscopic techniques offer an ideal method of detecting chemicals without using a sample
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