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16211

Sigma-Aldrich

Tetrachloroethylene

≥99.5%

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Synonym(s):
PCE, Perchloroethylene
Linear Formula:
CCl2=CCl2
CAS Number:
127-18-4
Molecular Weight:
165.83
Beilstein:
1361721
EC Number:
204-825-9
MDL number:
MFCD00000834
PubChem Substance ID:
329751147

vapor density

5.83 (vs air)

Quality Level

100

vapor pressure

13 mmHg ( 20 °C)
19 mmHg ( 25 °C)

Assay

≥99.5%

form

liquid

contains

stabilizer

technique(s)

NMR: suitable

impurities

≤0.001% free acid (as HCl)
≤0.001% non-volatile matter
≤0.01% water (Karl Fischer)

refractive index

n20/D 1.505 (lit.)

bp

121 °C (lit.)

mp

−22 °C (lit.)

density

1.623 g/mL at 25 °C (lit.)

SMILES string

Cl\C(Cl)=C(\Cl)Cl

InChI

1S/C2Cl4/c3-1(4)2(5)6

InChI key

CYTYCFOTNPOANT-UHFFFAOYSA-N

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General description

Tetrachloroethylene is a chlorinated ethene derivative mainly found in the contaminated groundwater due to its extensive use as a dry cleaning solvent. Its sorption and reduction kinetics with zero-valent iron has been determined in a closed, anaerobic batch system.
Tetrachloroethylene, a chlorinated ethylene, is a common industrial solvent. It is also one of the major contaminant found in groundwater supplies.

Application

TCE may be used as a metal cleaning or degreasing agent.
Tetrachloroethylene (TCE) was employed as solvent to investigate the NMR spectra of end functionalized cyclopentadienyl poly(ethylene) (PE-Cp).

Signal Word

Warning

Hazard Classifications

Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

No data available

Flash Point(C)

No data available

Regulatory Information

危险化学品

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Dechlorination of tetrachloroethylene by palladized iron in the presence of humic acid.
Doong RA and Lai TJ.
Water Research, 39(11), 2309-2318 (2005)
Source apportionment of groundwater pollution in a city's eastern part using multivariate statistical techniques.
Jiang P, et al.
IOP Conference Series: Earth and Environmental Science., 59(1) (2017)
Synthesis of Cyclopentadienyl Capped Polyethylene and Subsequent Block Copolymer Formation Via Hetero Diels-Alder (HDA) Chemistry.
Espinosa E, et al.
Macromolecular Rapid Communications, 32(18), 1447-1453 (2011)
Use of exhaled air as an improved biomonitoring method to assess perchloroethylene short-term exposure.
Dias CM, et al.
Environmental Research, 156, 108-112 (2017)
Fan Chen et al.
Frontiers in microbiology, 9, 2306-2306 (2018-10-17)
Bioelectrochemical systems (BESs) are regarded as a promising approach for the enhanced dechlorination of chlorinated aliphatic hydrocarbons (CAHs). However, the electron distribution and transfer considering dechlorination, methanogenesis, and other bioprocesses in these systems are little understood. This study investigated the
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