327956
(1R)-(+)-诺蒎酮
98%
别名:
6,6-二甲基二环[3.1.1]庚-2-酮
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关于此项目
经验公式（希尔记法）:
C9H14O
化学文摘社编号:
分子量:
138.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352115
MDL number:
Assay:
98%
Form:
liquid
产品名称
(1R)-(+)-诺蒎酮, 98%
InChI
1S/C9H14O/c1-9(2)6-3-4-8(10)7(9)5-6/h6-7H,3-5H2,1-2H3/t6-,7-/m0/s1
SMILES string
CC1(C)[C@H]2CCC(=O)[C@@H]1C2
InChI key
XZFDKWMYCUEKSS-BQBZGAKWSA-N
assay
98%
form
liquid
optical activity
[α]20/D +16°, neat
refractive index
n20/D 1.479 (lit.)
bp
209 °C (lit.)
density
0.981 g/mL at 25 °C (lit.)
functional group
ketone
storage temp.
2-8°C
Quality Level
Application
(1R)-(+)-降蒎酮可用于制备手性环化的茚衍生物，该衍生物可能是不对称转化中过渡金属配合物的潜在有用的手性配体。它也可以与仲胺在环己烷中反应形成相应的烯胺。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
167.0 °F - closed cup
flash_point_c
75 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Boranes in synthesis-VII. Synthesis of 2-dialkylamino-6, 6-dimethylbicyclo [3.1. 1] heptan-3-ols from (R)-(+)-nopinone. Chiral auxiliaries for the addition of diethylzinc to aromatic aldehydes.
Goralski CT, et al.
Tetrahedron Asymmetry, 8(23), 3863-3871 (1997)
Synthesis of (1R)-(+)-nopinone-and (1S)-(-)-verbenone-derived chiral annulated indenes via electrocyclic reactions.
Liu C and Sowa JR.
Tetrahedron Letters, 37(40), 7241-7244 (1996)
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