495301
(+)-2,2′-异亚丙基双[(4R)-4-苄基-2-噁唑啉]
98%
别名:
(R,R)-(+)-2,2′-异亚丙基双(4-苄基-2-噁唑啉), [R(R*,R*)]-(+)-2,2′-异亚丙基双(4-苄基-2-噁唑啉)
选择尺寸
关于此项目
产品名称
(+)-2,2′-异亚丙基双[(4R)-4-苄基-2-噁唑啉], 98%
InChI
1S/C23H26N2O2/c1-23(2,21-24-19(15-26-21)13-17-9-5-3-6-10-17)22-25-20(16-27-22)14-18-11-7-4-8-12-18/h3-12,19-20H,13-16H2,1-2H3/t19-,20-/m1/s1
SMILES string
CC(C)(C1=N[C@@H](CO1)Cc2ccccc2)C3=N[C@@H](CO3)Cc4ccccc4
InChI key
GAKCKAKYRQUVRK-WOJBJXKFSA-N
assay
98%
optical activity
[α]22/D +65°, c = 1 in ethanol
mp
54-60 °C (lit.)
functional group
ether
phenyl
storage temp.
2-8°C
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
BOX ligand complex enhances catalytic enantioselective aziridination of styrene, with phenyl substituents proving superior over t-Bu groups.
使用络合Cu(I)OTf的BOX配体进行不对称催化苯乙烯合成氮杂环丙烷的反应，BOX配体带苯基取代基的优于具有位阻需求的叔丁(t-Bu)基团。
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