104655
1,1′-联-2-萘酚
99%
别名:
(±)-1,1′-联萘-2,2′-二醇, (±)-2,2′-二羟基-1,1′-联萘, 2,2′-二萘醚, 2,2′-联萘酚, BINOL
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关于此项目
线性分子式:
HOC10H6C10H6OH
化学文摘社编号:
分子量:
286.32
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-014-0
Beilstein/REAXYS Number:
997518
MDL number:
InChI key
PPTXVXKCQZKFBN-UHFFFAOYSA-N
InChI
1S/C20H14O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,21-22H
SMILES string
Oc1ccc2ccccc2c1-c3c(O)ccc4ccccc34
assay
99%
reaction suitability
reagent type: ligand
mp
214-217 °C (lit.)
Quality Level
Application
用于不对称迈克尔加成反应的手性配体和助剂；对映选择性 Diels-Alder 反应；炔基。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
BINOL: a versatile chiral reagent.
Jean Michel Brunel
Chemical reviews, 105(3), 857-897 (2005-03-10)
Yifeng Zhou et al.
Organic letters, 6(23), 4147-4149 (2004-11-05)
The readily available and inexpensive (S)-BINOL ligand in combination with Ti(O(i)Pr)(4) is an effective chiral catalyst for the catalytic asymmetric addition of alkynylzinc to unactivated simple ketones. Good to excellent enantioselectivities were achieved. No previous case has been reported successfully
Sang-Mi Jeong et al.
Journal of the American Chemical Society, 130(11), 3497-3501 (2008-02-22)
Monolayers of 1,1'-bi-2-naphthol (BN) derivatives, of which the two naphthalene rings are twisted along the carbon(1)-carbon(1') single bond, were studied for their conformational effect on the growth of pentacene crystals on their monolayer surface. BN monolayers with H and Br
Andrew C Meng et al.
Journal of molecular recognition : JMR, 22(2), 121-128 (2009-02-06)
One monomer molecularly imprinted polymers (OMNiMIPs) have enhanced binding and selectivity properties versus traditionally formulated ethylene glycol dimethacrylate (EGDMA)/methacrylic acid (MAA) imprinted polymers. Further comparison was investigated toward multi-analyte imprinting capability of these two imprinted materials. Two templates, (R)-(+)-1,1'-bi-2-naphthol and
Wen Weng et al.
Journal of chromatography. A, 1210(2), 178-184 (2008-10-07)
Seven binaphthyl compounds were enantioseparated by HPLC with an immobilized polysaccharide-based chiral stationary phase, Chiralpak IA. The experiments were performed under normal-phase conditions. Effects of polar modifier and column temperature on the retention time and separation factor were evaluated. All
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