106399
1-金刚烷甲酸
99%
别名:
Adamantane carboxylic acid
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关于此项目
经验公式（希尔记法）:
C11H16O2
化学文摘社编号:
分子量:
180.24
Beilstein:
1910637
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
mp
172-174 °C (lit.)
官能团
carboxylic acid
SMILES字符串
OC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C11H16O2/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2,(H,12,13)/t7-,8+,9-,11-
InChI key
JIMXXGFJRDUSRO-KJZNFTALSA-N
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应用
1-金刚烷甲酸可用于：
- 在单分散、高结晶度的CoPt3纳米颗粒和多孔铂纳米颗粒合成中用作稳定剂。
- 作为缩聚反应添加剂，生成共轭聚合物作为光电材料。
- 作为水介质中钯催化烯丙基取代反应的添加剂。
生化/生理作用
1-金刚烷羧酸与环己烷多糖发生络合反应。它是苯酯水解环七直链淀粉的抑制剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Masaki Nakahata et al.
Nature communications, 2, 511-511 (2011-10-27)
Expanding the useful lifespan of materials is becoming highly desirable, and self-healing and self-repairing materials may become valuable commodities. The formation of supramolecular materials through host-guest interactions is a powerful method to create non-conventional materials. Here we report the formation
Thomas Le Saux et al.
Electrophoresis, 26(16), 3094-3104 (2005-07-26)
Among the different experimental strategies available in capillary electrophoresis (CE) to determine binding parameters, affinity capillary electrophoresis (ACE) has been the most widely embraced due to its easiness of implementation and of data handling. Ligand-substrate binding constants are thus directly
Birgit Hakkarainen et al.
Carbohydrate research, 340(8), 1539-1545 (2005-05-12)
The hydrogen-bond network in mono-altro-beta-cyclodextrin and in its inclusion complex with adamantane-1-carboxylic acid were investigated by (1)H NMR spectroscopy using the chemical shifts, temperature coefficients and vicinal coupling constants of the exchangeable hydroxy protons. The chemical shifts of the 3-OH
Daniel Harries et al.
Journal of the American Chemical Society, 127(7), 2184-2190 (2005-02-17)
Using microcalorimetry, we follow changes in the association free energy of beta-cyclodextrin (CD) with the hydrophobic part of adamantane carboxylate (AD) due to added salt or polar (net-neutral) solutes that are excluded from the molecular interacting surfaces. Changes in binding
Detailed optimization of polycondensation reaction via direct C-H arylation of ethylenedioxythiophene
Yamazaki K, et al.
Macromolecular Rapid Communications, 34(1), 69-73 (2013)
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