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安全信息

109975

Sigma-Aldrich

1,2-环氧丁烷

99%

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别名:
1-丁烯氧化物, 乙基环氧乙烷, 氧化丁烯, 环氧丁烷
经验公式（希尔记法）:
C4H8O
CAS号:
106-88-7
分子量:
72.11
Beilstein:
102411
EC 号:
203-438-2
MDL编号:
MFCD00005153
PubChem化学物质编号:
24846950
NACRES:
NA.23

蒸汽密度

2.2 (vs air)

蒸汽压

140 mmHg ( 20 °C)

检测方案

99%

自燃温度

698 °F

expl. lim.

19 %

折射率

n20/D 1.384 (lit.)

bp

63 °C (lit.)

密度

0.829 g/mL at 25 °C (lit.)

SMILES string

CCC1CO1

InChI

1S/C4H8O/c1-2-4-3-5-4/h4H,2-3H2,1H3

InChI key

RBACIKXCRWGCBB-UHFFFAOYSA-N

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相关类别

应用

1,2-环氧丁烷可用于：
  • 作为单体通过开环聚合反应合成新引发剂。 这些引发剂可用于制备复杂大分子，如接枝聚酰胺。
  • 聚乙烯亚胺的功能化，聚乙烯亚胺可用于合成CO2 捕集用的氧化稳定性吸附剂。

特点和优势

  • 高可聚合性
  • 低转移反应易感性
  • 易处理

警示用语：

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

5.0 °F - closed cup

闪点(°C)

-15 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves

法规信息

危险化学品

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M Katz et al.
Journal of environmental pathology and toxicology, 3(5-6), 171-187 (1980-06-01)
Nitrosopiperidine, sodium nitrite and 1,2 epoxybutane were tested in the Ames agar incorporation assay in an attempt to establish exact criteria for detecting the activity of these weak mutagens. As regards minimum concentrations it was determined that at 500 microgram
Hong Yuan Sun et al.
Carbohydrate research, 344(15), 1999-2004 (2009-08-26)
A new soluble cyclodextrin derivative 6-O-(2-hydroxybutyl)-beta-cyclodextrin (6-HB-beta-CD) was prepared. Its molecular binding and recognition ability were investigated with the comparison of beta-cyclodextrin (beta-CD), 2-O-(2-hydroxypropyl)-beta-cyclodextrin (2-HP-beta-CD), 6-O-(2-hydroxypropyl)-beta-cyclodextrin (6-HP-beta-CD), and 2-O-(2-hydroxybutyl)-beta-cyclodextrin (2-HB-beta-CD). The relationship between the complex stability constants and the possible
T Nakamura et al.
Biochemical and biophysical research communications, 180(1), 124-130 (1991-10-15)
Halohydrin hydrogen-halide-lyase, which catalyzes the interconversion of halohydrins to epoxides, purified from a recombinant E. coli was found to catalyze the transformation of 1,2-epoxybutane into beta-hydroxyvaleronitrile in the presence of cyanide. Chloride inhibited competitively the formation of beta-hydroxyvaleronitrile. The enzyme
A M Rossi et al.
Teratogenesis, carcinogenesis, and mutagenesis, 3(1), 75-87 (1983-01-01)
In vivo and in vitro methodologies that have employed the yeast Schizosaccharomyces pombe as genetic indicator have been utilized to investigate the mutagenicity of two trichloroethylene (TCE) samples of pure and technical grade. Mutagenicity assays were also performed on two
D B McGregor et al.
Environmental and molecular mutagenesis, 13(3), 197-202 (1989-01-01)
Trichloroethylene (TCE) is a high production volume chemical frequently stabilized with oxiranes. These oxiranes may be responsible for the mutagenic activity of TCE in Salmonella, which has been occasionally, but not consistently, reported. High purity and oxirane-stabilized TCE samples were
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