111627
2-甲基-1-己烯
96%
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关于此项目
线性分子式:
CH3(CH2)3C(CH3)=CH2
化学文摘社编号:
分子量:
98.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-041-1
Beilstein/REAXYS Number:
1732738
MDL number:
产品名称
2-甲基-1-己烯, 96%
InChI key
IRUDSQHLKGNCGF-UHFFFAOYSA-N
InChI
1S/C7H14/c1-4-5-6-7(2)3/h2,4-6H2,1,3H3
SMILES string
CCCCC(C)=C
vapor density
1 (vs air)
assay
96%
refractive index
n20/D 1.403 (lit.)
bp
92 °C (lit.)
density
0.697 g/mL at 25 °C (lit.)
Quality Level
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General description
2-Methyl-1-hexene is a less reactive olefin that is hydroformylated in the presence of phosphite-modified rhodium catalysts. The epoxidation of 2-methyl-1-hexene is catalyzed by human and rat P450 enzymes.
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
17.6 °F - closed cup
flash_point_c
-8 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Hydroformylation of less reactive olefins with modified rhodium catalysts.
Van Leeuwen PWNM and Roobeek CF.
Journal of Organometallic Chemistry, 258(3), 343-350 (1983)
C Chiappe et al.
Chemical research in toxicology, 11(12), 1487-1493 (1998-12-22)
The epoxidation of 1-hexene (1a) and 2-methyl-1-hexene (1b), two hydrocarbons present in the ambient air as pollutants, is catalyzed by some human and rat P450 enzymes. The enantioselectivities of these processes, when the reactions were carried out using rat and
Hiroshi Toda et al.
Applied and environmental microbiology, 81(6), 1919-1925 (2015-01-04)
We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the organic solvent-tolerant microorganism Kocuria rhizophila DC2201, and the bioconversion reaction was performed in an
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