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经验公式(希尔记法):
C8H7NS
化学文摘社编号:
分子量:
149.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-423-3
Beilstein/REAXYS Number:
112427
MDL number:
产品名称
2-甲基苯并噻唑, 99%
InChI key
DXYYSGDWQCSKKO-UHFFFAOYSA-N
InChI
1S/C8H7NS/c1-6-9-7-4-2-3-5-8(7)10-6/h2-5H,1H3
SMILES string
Cc1nc2ccccc2s1
assay
99%
refractive index
n20/D 1.617 (lit.)
bp
238 °C (lit.)
mp
11-14 °C (lit.)
density
1.173 g/mL at 25 °C (lit.)
Quality Level
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Application
用于合成聚碳菁、噻菁染料以及(芳呋喃基)苯并噻唑的试剂。
General description
可以使用常规法和微波加热法通过Cu催化的无碱C-S偶联对2-甲基苯并噻唑进行合成。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
215.6 °F - closed cup
flash_point_c
102 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Monatshefte fur Chemie / Chemical Monthly, 125, 209-209 (1994)
Zh. Org. Khim., 28, 2159-2159 (1992)
Chem. Abstr., 120, 194030z-194030z (1994)
Youji Huaxue, 14, 59-59 (1994)
Silvia M Soria-Castro et al.
Beilstein journal of organic chemistry, 9, 467-475 (2013-03-19)
S-aryl thioacetates can be prepared by reaction of inexpensive potassium thioacetate with both electron-rich and electron-poor aryl iodides under a base-free copper/ligand catalytic system. CuI as copper source affords S-aryl thioacetates in good to excellent yields, by using 1,10-phenanthroline as
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