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Merck
CN

124109

1-溴-2-甲基萘

technical grade, 90%

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线性分子式:
CH3C10H6Br
化学文摘社编号:
分子量:
221.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-966-1
Beilstein/REAXYS Number:
2042531
MDL number:
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产品名称

1-溴-2-甲基萘, technical grade, 90%

InChI key

CMIMBQIBIZZZHQ-UHFFFAOYSA-N

InChI

1S/C11H9Br/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,1H3

SMILES string

Cc1ccc2ccccc2c1Br

grade

technical grade

assay

90%

form

liquid

refractive index

n20/D 1.648 (lit.)

bp

296 °C (lit.)

density

1.418 g/mL at 25 °C (lit.)

functional group

bromo

Quality Level

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Application

1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry.

General description

Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl.

pictograms

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signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

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Synthesis of chiral binaphthalenes using the asymmetric Suzuki reaction.
Cammidge AN and Crepy KVL.
Tetrahedron, 60(20), 4377-4386 (2004)
Determination of halogenated compounds with supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
Olson LK and Caruso JA.
Journal of Analytical Atomic Spectrometry, 7(6), 993-998 (1992)
N A Vinokurova
Voprosy onkologii, 21(3), 19-24 (1975-01-01)
The author presents an analysis of the results of the combination chemotherapy with natulan, vincristin, novembichine and prednisolone in 43 patients showing generalized lymphogranulomatosis, mainly with recurrences following radiation and chemotherapy with different antitumor substances. The results of the combination

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