125199
3-氯丙烷磺酰氯
98%
别名:
γ-Chloropropanesulfonyl chloride, 1-Chloro-3-propanesulfonyl chloride, 3-Chloro-1-propanesulfonyl chloride, 3-Chloro-n-propanesulfonyl chloride, 3-Chloropropylsulfonyl chloride
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关于此项目
线性分子式:
Cl(CH2)3SO2Cl
化学文摘社编号:
分子量:
177.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-646-3
Beilstein/REAXYS Number:
1754119
MDL number:
产品名称
3-氯丙烷磺酰氯, 98%
InChI key
GPKDGVXBXQTHRY-UHFFFAOYSA-N
InChI
1S/C3H6Cl2O2S/c4-2-1-3-8(5,6)7/h1-3H2
SMILES string
ClCCCS(Cl)(=O)=O
assay
98%
form
liquid
refractive index
n20/D 1.489 (lit.)
bp
70 °C/0.5 mmHg (lit.)
density
1.456 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
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Application
3-Chloropropanesulfonyl chloride was used as starting reagent in the synthesis of the pyrrolidine-based chiral imidazolium ionic liquid. It was also used in sulfonation of cross-linked polyethylenimine for selective removal of Hg. It was used in generation and trapping of the derived sulfene with imines and glyoxylates in the presence of chinchona alkaloids to yield chiral sultams and sultones.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Catalytic enantio- and diastereoselective formation of beta-sultones: ring-strained precursors for enantioenriched beta-hydroxysulfonyl derivatives.
Florian M Koch et al.
Angewandte Chemie (International ed. in English), 46(15), 2685-2689 (2007-03-03)
Functionalized chiral ionic liquid as recyclable organocatalyst for asymmetric Michael addition to nitrostyrenes.
Ni B, et al.
Green Chemistry, 9(7), 737-739 (2007)
Sulfonated cross-linked polyethylenimine for selective removal of mercury from aqueous solutions.
Saad DMG, et al.
Toxicological & Environmental Chemistry, 94(10), 1916-1929 (2012)
Xolisiwe Sebutsoe et al.
Chemosphere, 266, 128975-128975 (2020-11-25)
Arsenic and selenium are both carcinogenic and their presence in fresh water has attracted the development of robust and accurate monitoring techniques. A new diffusive gradients in thin-films (DGT) sampler was developed and evaluated for the in situ measurements of
Marian Zajac et al.
Organic letters, 9(10), 2007-2010 (2007-04-24)
beta-Sultams, highly strained sulfonyl analogues of beta-lactams, were prepared enantio- and diastereoselectively by tertiary amine catalyzed [2 + 2] cycloaddition reactions. The title compounds are practical precursors of highly enantioenriched biologically interesting beta-aminosulfonyl derivatives.
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