125598
1,4-环己烷二甲醇
mixture of cis and trans, 99%
别名:
1,4-二(羟甲基)环己烷，顺反异构体混合物
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关于此项目
线性分子式:
C6H10(CH2OH)2
化学文摘社编号:
分子量:
144.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-268-9
Beilstein/REAXYS Number:
1902271
MDL number:
产品名称
1,4-环己烷二甲醇, mixture of cis and trans, 99%
InChI key
YIMQCDZDWXUDCA-UHFFFAOYSA-N
InChI
1S/C8H16O2/c9-5-7-1-2-8(6-10)4-3-7/h7-10H,1-6H2
SMILES string
OCC1CCC(CO)CC1
vapor density
5 (vs air)
assay
99%
autoignition temp.
584 °F
bp
283 °C (lit.)
functional group
hydroxyl
Quality Level
Application
1,4-环己烷二甲醇已用于聚缩酮共聚物的合成。在基于1,3-亚丙基-co-1,4-环己烷二亚甲基琥珀酸酯的聚酯 - 碳酸酯的合成过程中，被用作二醇共聚单体。
General description
1,4-环己烷二甲醇广泛用作聚合物工业中的交联剂。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
321.8 °F - closed cup
flash_point_c
161 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
Pingfan Li et al.
Chemical communications (Cambridge, England), (36)(36), 5412-5414 (2009-09-03)
The silica gel absorbed amino acid salt catalyzed asymmetric intramolecular Robinson annulation reaction has been developed; up to 97% ee was obtained with this readily recoverable organocatalyst.
Eric J Moskala
Medical device technology, 14(3), 12-16 (2003-06-07)
Gamma irradiation affects colour, most notably b, and total transmittance of all of the copolyesters used in this study. The changes in colour and total transmittance increase with increasing dose level and CHDM content of the copolyester. These changes are
Pu Wang et al.
Biomaterials science, 6(5), 1262-1270 (2018-04-17)
One of the major challenges in anticancer therapy is the poor penetration of anticancer drugs into tumors, especially in solid tumors, resulting in decreased therapeutic efficacy in vivo. To solve some of these problems, in this study, a dual-responsive polymeric
S L Sendelbeck et al.
Drug metabolism and disposition: the biological fate of chemicals, 13(3), 291-295 (1985-05-01)
Disposition of the 14C-labeled bioerodible polymer poly(2,2-dioxy-cis,trans-1,4-cyclohexane dimethylene tetrahydrofuran) (ALZAMER C101ct) and its ultimate hydrolysis products, 4-hydroxybutyrate (4HB) and cis,trans-1,4-bis(hydroxymethyl)cyclohexane (CHDM), was assessed in vivo in rats 24 hr after sc administration of the 14C-labeled polymer or hydrolysis products. The
Mingliang Ding et al.
Biodegradation, 23(1), 127-132 (2011-07-07)
Enzymatic hydrolytic degradation of polybutylene succinate (PBS), poly(polybutylenesuccinate-co-1,4-cyclohexane dimethanol) (PBS/CHDM) and poly(polybutylene succinate-co-diglycolic acid) (PBS/DGA) in mixed solvent of tetrahydrofuran (THF) and toluene was examined. Lipase was used as catalyst to degrade polymers with molecular weight of more than 100,000
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