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经验公式(希尔记法):
C14H12
化学文摘社编号:
分子量:
180.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-336-1
Beilstein/REAXYS Number:
1364575
MDL number:
产品名称
9,10-二氢蒽, 97%
InChI key
WPDAVTSOEQEGMS-UHFFFAOYSA-N
InChI
1S/C14H12/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-8H,9-10H2
SMILES string
C1c2ccccc2Cc3ccccc13
assay
97%
form
solid
bp
312 °C (lit.)
mp
103-107 °C (lit.)
density
0.88 g/mL at 25 °C (lit.)
Quality Level
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Application
9,10-二氢蒽(DHA)长期用于在研究中评估 MeCN 中价离域铁络合物的夺氢能力。
General description
在 [7H] 苯并蒽催化剂存在下,9,10-二氢蒽可引起 C60 和 C70 的转移氢化。在作为氧化剂的分子氧和作为二甲苯中的促进剂的活性炭存在下,它被氧化芳构化为相应的蒽。
Genqiang Xue et al.
Proceedings of the National Academy of Sciences of the United States of America, 104(52), 20713-20718 (2007-12-21)
Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(mu-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in
Nirupama Singh et al.
Journal of inorganic biochemistry, 197, 110674-110674 (2019-05-21)
Developing coordination complexes of earth abundant metals that can perform substrate oxidations under benign conditions is an ongoing challenge. Herein, the reactivity of two mononuclear Cu-complexes toward the oxidant H2O2 is reported. Both complexes displayed ligand oxidation upon reaction with
Pengfei Sun et al.
Small (Weinheim an der Bergstrasse, Germany), 16(3), e1906462-e1906462 (2019-12-24)
Lithium primary batteries are still widely used in military, aerospace, medical, and civilian applications despite the omnipresence of rechargeable Li-ion batteries. However, these current primary chemistries are exclusively based on inorganic materials with high cost, low energy density or severe
Natsuki Nakamichi et al.
The Journal of organic chemistry, 68(21), 8272-8273 (2003-10-11)
Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco KB, Aldrich, Inc.) as a promoter in xylene.
[7H] Benzanthrone, a catalyst for the transfer hydrogenation of C60 and C70 by 9, 10-dihydroanthracene.
Gerst M, et al.
Tetrahedron Letters, 34(48), 7729-7732 (1993)
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