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文件

128422

Sigma-Aldrich

富马酸单乙酯

95%

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别名:
反丁烯二酸单乙酯, 富马酸氢乙酯
线性分子式:
C2H5OCOCH=CHCOOH
CAS号:
2459-05-4
分子量:
144.13
Beilstein:
1723588
EC 号:
219-544-7
MDL编号:
MFCD00002699
PubChem化学物质编号:
24847858

质量水平

100

检测方案

95%

形式

solid

bp

147 °C/16 mmHg (lit.)

mp

66-68 °C (lit.)

SMILES string

CCOC(=O)\C=C\C(O)=O

InChI

1S/C6H8O4/c1-2-10-6(9)4-3-5(7)8/h3-4H,2H2,1H3,(H,7,8)/b4-3+

InChI key

XLYMOEINVGRTEX-ONEGZZNKSA-N

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相关类别

应用

富马酸单乙酯（富马酸单乙酯，富马酸单乙酯）可用于制备可光交联的大分子单体。它也用于合成 Ugi/分子间 Diels-Alder（IMDA）环加成产物。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 1

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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K Paulvannan
The Journal of organic chemistry, 69(4), 1207-1214 (2004-02-14)
An efficient approach to rigid tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder (IMDA) cycloaddition of pyrrole is described. The one-pot Ugi four-component condensation (4CC) reaction was used as the key transformation to prepare trienes with a carboxamide substituent
A Kreuter et al.
The British journal of dermatology, 153(4), 802-807 (2005-09-27)
Necrobiosis lipoidica (NL) is an uncommon granulomatous skin disease with association to diabetes mellitus. To date, no proven effective therapy for NL has been implemented. The standard treatment is topical application of corticosteroids, but numerous agents have been reported for
U Mrowietz et al.
The British journal of dermatology, 138(3), 456-460 (1998-05-15)
Systemic treatment of psoriasis with fumaric acid esters (FAE) has been found effective by empirical means. In recent years clinical studies have confirmed the antipsoriatic activity of a defined mixture of different FAE. The aim of the present prospective multicentre
P J Altmeyer et al.
Journal of the American Academy of Dermatology, 30(6), 977-981 (1994-06-01)
Psoriasis vulgaris may benefit from treatment with fumaric acid and/or its derivatives; however, because different preparations have been used, results have been contradictory and difficult to interpret. The purpose of this clinical trial was to evaluate the therapeutic value of
M Vandermeeren et al.
Biochemical and biophysical research communications, 234(1), 19-23 (1997-05-08)
Most studies on the antipsoriatic mode of action of dimethylfumarate focused on its antiproliferative effects in keratinocytes. Because inflammatory skin diseases are associated with an upregulation of endothelial cell adhesion molecules and because the presence of inflammatory cells in dermis
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