136131
1,2-二甲基咪唑
97%
别名:
1,2-Dimethyl-1H-imidazole, 1,2DMZ
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关于此项目
经验公式（希尔记法）:
C5H8N2
化学文摘社编号:
分子量:
96.13
EC 号:
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
蒸汽压
1 mmHg ( 20 °C)
方案
97%
表单
solid
自燃温度
896 °F
沸点
204 °C (lit.)
mp
37-39 °C (lit.)
密度
1.084 g/mL at 25 °C (lit.)
SMILES字符串
Cc1nccn1C
InChI
1S/C5H8N2/c1-5-6-3-4-7(5)2/h3-4H,1-2H3
InChI key
GIWQSPITLQVMSG-UHFFFAOYSA-N
一般描述
1,2-二甲基咪唑与四乙酸铜 (II) 反应生成 顺式 - 双 （乙酸酯） 双 （1,2-二甲基咪唑）铜 (II) 络合物 。它与溴苄发生缅舒特金反应生成 3-苄基-1,2-二甲基咪唑溴化物，并在各种离子液体和分子有机溶剂中研究了反应动力学 。
应用
1,2-二甲基咪唑用于合成 1,2-二甲基-3- n -丁基咪唑氯化物和 1,2-二甲基-3- n -丙基咪唑氯化物 。它也用于合成 1-（2-甲氧基乙基）-2,3-二甲基咪唑氯化物和六氟磷酸盐 。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
197.6 °F - closed cup
闪点(°C)
92 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
The coordination environment of mitochondrial cytochromes b.
K R Carter et al.
FEBS letters, 132(2), 243-246 (1981-09-28)
Wesley A Henderson et al.
Chemical communications (Cambridge, England), (35)(35), 3708-3710 (2006-10-19)
The crystal structures and thermal behavior of the 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexa-fluorophosphate salts are compared with the analogous 1-butyl-2,3-dimethylimidazolium salts to examine the influence of the ether oxygen on salt thermal properties for a typical constituent cation used in the
M M Fitzgerald et al.
Protein science : a publication of the Protein Society, 4(9), 1844-1850 (1995-09-01)
The activated state of cytochrome c peroxidase, compound ES, contains a cation radical on the Trp-191 side chain. We recently reported that replacing this tryptophan with glycine creates a buried cavity at the active site that contains ordered solvent and
Alain Lesimple et al.
Journal of mass spectrometry : JMS, 43(1), 35-41 (2007-07-10)
A number of 1,2-dimethylimidazole ionic liquids substituted on N(II) with alkyl chains of varying lengths terminated with sulfur-containing groups were investigated by electrospray high-resolution tandem Fourier-transform mass spectrometry. Fragmentation pathways are strongly dependent on the oxidation state of the sulfur
Melissa Coles et al.
In vivo (Athens, Greece), 19(4), 661-665 (2005-07-08)
Celecoxib (C), a COX-2 enzyme inhibitor, was administered at a 0.1% dose level in the diet of female Swiss Webster CFW outbred mice for life. The mice also received 1,2-dimethylhydrazine dihydrochloride (1,2-DMH) as 10 weekly subcutaneous injections at 20 microg/g
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