140333
苄基-2,2,2-三氯乙酰亚氨酸酯
≥96%
别名:
2,2,2-三氯乙酰亚胺苄酯
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关于此项目
线性分子式:
CCl3C(=NH)OCH2C6H5
化学文摘社编号:
分子量:
252.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2525375
产品名称
苄基-2,2,2-三氯乙酰亚氨酸酯, ≥96%
InChI
1S/C9H8Cl3NO/c10-9(11,12)8(13)14-6-7-4-2-1-3-5-7/h1-5,13H,6H2
SMILES string
ClC(Cl)(Cl)C(=N)OCc1ccccc1
InChI key
HUZCTWYDQIQZPM-UHFFFAOYSA-N
assay
≥96%
form
liquid
impurities
<1% benzyl alcohol
refractive index
n20/D 1.545 (lit.)
bp
106-114 °C/0.5 mmHg (lit.)
transition temp
solidification point 3-4 °C
density
1.359 g/mL at 25 °C (lit.)
functional group
chloro
ether
phenyl
storage temp.
2-8°C
Quality Level
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Application
2，2，2-三氯乙酰亚胺苄酯可用在合成索青霉素二甲醚和（S）-3-（苄氧基）-2-甲基丙醛的过程中。它也用于酸催化羟基的苄基化反应。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Studies of novel cyclitols. A synthesis of 3'O, 4'O -dimethylfuniculosin.
Williams DR, et al.
Tetrahedron Letters, 41(49), 9397-9401 (2000)
The total synthesis of scytophycin C. Part 1: stereocontrolled synthesis of the C1? C32 protected seco acid.
Paterson I, et al.
Tetrahedron, 54(39), 11935-11954 (1998)
Tetrahedron Asymmetry, 3, 1547-1547 (1992)
商品
Trichloroacetimidates are also commonly employed as alcohol alkylation reagents, particularly when existing functionality is not acid sensitive.
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