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141615

4-硝基咪唑

Name: 4-硝基咪唑
Brand: ALDRICH

97%

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经验公式（希尔记法）:

C₃H₃N₃O₂

CAS号:

3034-38-6

分子量:

113.07

Beilstein:

2815

EC 号:

221-224-7

MDL编号:

MFCD00005196

PubChem化学物质编号:

24848505

NACRES:

NA.22

检测方案

97%

形式

powder

mp

303 °C (dec.) (lit.)

SMILES string

[O-][N+](=O)c1c[nH]cn1

InChI

1S/C3H3N3O2/c7-6(8)3-1-4-2-5-3/h1-2H,(H,4,5)

InChI key

VYDWQPKRHOGLPA-UHFFFAOYSA-N

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一般描述

4-硝基咪唑是1-甲基-2,4,5-三硝基咪唑合成过程中的中间体。

应用

4-硝基咪唑被用于研究以双(2,4,6-三氯苯基)草酸酯为试剂时，杂环化合物在过氧草酸酯化学发光反应中的催化效率。

907197

1,4-Dinitro-1-imidazole

象形图

GHS07

警示用语：

Warning

危险声明

H302

预防措施声明

P264 - P270 - P301 + P312 - P501

危险分类

Acute Tox. 4 Oral

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

392.0 °F - closed cup

闪点(°C)

200 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

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示例

T1503

货号

25G

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Quantum-chemical studies on thermodynamic feasibility of 1-methyl-2,4,5-trinitroimidazole processes.

Pandurang M Jadhav et al.

Journal of molecular modeling, 19(8), 3027-3033 (2013-04-12)

1-Methyl-2,4,5-trinitro imidazole (MTNI) is a well-known melt cast explosive possessing good thermal stability and impact insensitivity. MTNI has been synthesized from multi-step nitration followed by methylation of imidazole exhibiting low yield. It is desirable to screen the process thermodynamically for

Heterocyclic compounds as catalysts in the peroxyoxalate chemiluminescence reaction of bis (2, 4, 6-trichlorophenyl) oxalate.

Jonsson T and Irgum K.

Analytica Chimica Acta, 361(3), 205-215 (1998)

Influence of ligand denticity on the properties of novel ⁹⁹mTc(I)-carbonyl complexes. Application to the development of radiopharmaceuticals for imaging hypoxic tissue.

Soledad Fernández et al.

Bioorganic & medicinal chemistry, 20(13), 4040-4048 (2012-06-05)

An important issue in the development of metal-based radiopharmaceuticals is the selection of the labelling strategy in order to couple the metal to the pharmacophore without losing the biological activity. With the aim to evaluate the correlation between ligand denticity

Synthesis and biological characterisation of novel dithiocarbamate containing 5-nitroimidazole (99m)Tc-complexes as potential agents for targeting hypoxia.

Javier Giglio et al.

Bioorganic & medicinal chemistry letters, 21(1), 394-397 (2010-11-23)

With the aim to develop new potential (99m)Tc-radiopharmaceuticals for imaging hypoxia based on the formation of Tc-nitrido complexes, two novel dithiocarbamate containing metronidazole derivatives (L1 and L2) have been prepared and characterised. The synthesis of L1 and L2 was achieved

Synthesis, in vitro and in vivo characterization of novel 99mTc-'4+1'-labeled 5-nitroimidazole derivatives as potential agents for imaging hypoxia.

Javier Giglio et al.

Nuclear medicine and biology, 39(5), 679-686 (2012-04-27)

The evaluation of oxygenation status of solid tumors is an important field of radiopharmaceutical research. With the aim to develop new potential 99mTc-radiopharmaceuticals for imaging hypoxia, we have synthesized two novel isocyanide derivatives of metronidazole, which has demonstrated high affinity

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