142670
氯甲基乙醚
95%
别名:
(Chloromethoxy)ethane, Ethoxychloromethane, Ethoxymethyl chloride, Ethyl chloromethyl ether
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关于此项目
线性分子式:
C2H5OCH2Cl
化学文摘社编号:
分子量:
94.54
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
221-687-5
MDL number:
产品名称
氯甲基乙醚, 95%
InChI key
FCYRSDMGOLYDHL-UHFFFAOYSA-N
InChI
1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
SMILES string
CCOCCl
assay
95%
form
liquid
refractive index
n20/D 1.404 (lit.)
bp
82 °C (lit.)
density
1.019 g/mL at 25 °C (lit.)
functional group
chloro
ether
storage temp.
2-8°C
Quality Level
Application
氯甲基乙醚可用于制备：
- 6-苄基-1-(乙氧基甲基）-5-碘嘧啶-2,4(1H,3H)-二酮，其是MKC-442类似物制备中的一种关键中间体。
- 通过与乙二醛-双-[(R)-1-(2-萘基)乙基]亚胺反应生成醇的酰化催化剂1,3-双-[(R)-1-(2-萘基）乙基氯化咪唑。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
66.2 °F - closed cup
flash_point_c
19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 10, 56-57 (2004-08-24)
Three Routes for the Synthesis of 6-Benzyl-1-ethoxymethyl-2, 4-dioxo-1, 2, 3, 4-tetrahydropyrimidine-5-carbaldehyde
Petersen L, et al.
Synthesis, 2001(04), 0559-0564 (2001)
K Takahashi et al.
Mutation research, 156(3), 153-161 (1985-06-01)
The mutagenic characteristics of formaldehyde on bacteria were examined. All the tester strains of Escherichia coli deficient in DNA-repair enzymes tested in the present study were significantly more sensitive to the killing effect of formaldehyde than the corresponding wild-type strain.
Chiral N-heterocyclic carbenes as asymmetric acylation catalysts
Suzuki Y, et al.
Tetrahedron, 62(2-3), 302-310 (2006)
Tadeusz J Szalaty et al.
International journal of biological macromolecules, 119, 431-437 (2018-07-29)
In this research we use ionic liquids in combination with mild process conditions to provide a selective increase in the content of carbonyl groups in the kraft lignin structure. Such modification can improve the properties of the pristine biopolymer. In
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