144819
1-(三甲基硅氧基)环己烯
99%
别名:
1-Cyclohexenyloxytrimethylsilane, 1-环己烯氧基三甲基硅烷
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关于此项目
线性分子式:
C6H9OSi(CH3)3
化学文摘社编号:
分子量:
170.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
229-675-1
Beilstein/REAXYS Number:
1859394
MDL number:
Assay:
99%
Form:
liquid
Quality Segment
assay
99%
form
liquid
refractive index
n20/D 1.447 (lit.)
bp
64-65 °C/15 mmHg (lit.)
density
0.875 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)OC1=CCCCC1
InChI
1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
InChI key
SBEMOANGDSSPJY-UHFFFAOYSA-N
General description
1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).
Application
1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ1,9- octalone. It is intermediate to many complex compounds including natural products.
