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Merck
CN

15140

双(2-氧代-3-噁唑烷基)次磷酰氯

≥97.0% (AT)

别名:

BOP-Cl, Phosphoric acid bis(2-oxooxazolidide) chloride

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关于此项目

经验公式(希尔记法):
C6H8ClN2O5P
化学文摘社编号:
分子量:
254.56
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3654596
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产品名称

双(2-氧代-3-噁唑烷基)次磷酰氯, ≥97.0% (AT)

InChI

1S/C6H8ClN2O5P/c7-15(12,8-1-3-13-5(8)10)9-2-4-14-6(9)11/h1-4H2

SMILES string

ClP(=O)(N1CCOC1=O)N2CCOC2=O

InChI key

KLDLRDSRCMJKGM-UHFFFAOYSA-N

assay

≥97.0% (AT)

form

solid

mp

191 °C (dec.) (lit.)

Quality Level

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Other Notes

活化羧基,合成酰胺、酯、肽 的试剂

Application

Bis(2-oxo-3-oxazolidinyl)phosphinic chloride was used in the preparation of hexadepsipeptide.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Zhao Yanbin et al.
Biochemical and biophysical research communications, 516(1), 102-111 (2019-06-16)
Here, we firstly examined the proliferation and invasion capacities of different osteosarcoma (OS) cell lines, and analyzed the profiling of the differentially expressed circular RNAs(circRNAs). Then, we identified a novel circRNA(circ_101356/circ_0004846, we named circSAMD4 in the present study) and found
S. Danishefsky et al
Tetrahedron Letters, 25, 4203-4203 (1984)
J. Cabre et al.
Synthesis, 413-413 (1984)
E.J. Corey et al.
Journal of the American Chemical Society, 104, 6818-6818 (1982)
Yanjie Xu et al.
Molecules (Basel, Switzerland), 10(1), 259-264 (2007-11-17)
Hexadepsipeptide 2, the precursor of Hirsutellide A (1), was synthesized in an overall yield of 45% from N-Boc-Me-Gly via three coupling reactions using dicyclohexylcarbodiimide (DCC), O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyl- uronium hexafluorophosphate (HATU) and bis(2-oxo-3-oxazolidinyl)phosphinic chloride (BOP-Cl), respectively.

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