1,2-亚苯基-次氯酸化膦

Name: 1,2-亚苯基-次氯酸化膦
Brand: ALDRICH

97%, solid

别名:

2-氯-1,3,2-苯并二氧环磷烯

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经验公式（希尔记法）:

C₆H₄ClO₂P

化学文摘社编号:

1641-40-3

分子量:

174.52

NACRES:

NA.22

PubChem Substance ID:

24849564

UNSPSC Code:

12352005

EC Number:

216-690-3

MDL number:

MFCD00005853

Beilstein/REAXYS Number:

135455

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产品名称

1,2-亚苯基-次氯酸化膦, 97%

InChI key

YUJYEGDMJZHLMY-UHFFFAOYSA-N

InChI

1S/C6H4ClO2P/c7-10-8-5-3-1-2-4-6(5)9-10/h1-4H

SMILES string

ClP1Oc2ccccc2O1

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

refractive index

n20/D 1.571 (lit.)

bp

80 °C/20 mmHg (lit.)

mp

30-35 °C (lit.)

density

1.466 g/mL at 25 °C (lit.)

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Application

Catalyst in synthesis of bakkane sesquiterpenes
Reactant in reversible halogen-halogen ligand substitution at room temperature, and in irreversible halogen-O substitution at higher temperatures
Reactant in preparation of gold(I) trimethoxybenzonitrile phosphine isolated precatalysts
Reactant for preparation of pyrroles by TMSOTf-catalyzed Arbuzov reaction
Phosphorylation agent
Reactant for reparation of vinyl-substituted spirophosphoranes and vinylphosphonates via Markovnikov addition