156671
叔丁醇钾
reagent grade, ≥98%
别名:
次丁氧基钾, 第三丁氧基钾
等级
reagent grade
质量水平
蒸汽压
1 mmHg ( 220 °C)
方案
≥98%
表单
solid
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
256-258 °C (dec.) (lit.)
溶解性
soluble
water: soluble (Hydrolysis, (rigorous decomposition))
环保替代产品分类
SMILES字符串
[K+].CC(C)(C)[O-]
InChI
1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI key
LPNYRYFBWFDTMA-UHFFFAOYSA-N
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一般描述
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处，查看更多详情。
应用
叔丁醇钾已作为强碱，用于通过N-叔丁基亚磺酰亚胺的转移氢化反应合成高对映体选择性的胺。
它也可用于：
它也可用于：
- 由酯和胺合成相应的脂肪和芳香酰胺。
- 在芳基醚、胺和酰胺的分子内环化中用作碱。
- 作为催化剂，通过芳基卤和烯烃的Mizoroki-Heck反应制备苯乙烯衍生物。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 2 - Skin Corr. 1A
补充剂危害
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
tert-Butoxide-assisted amidation of esters under green conditions
Kim Bo Ram, et al.
Synthesis, 44(01), 42-50 (2012)
"Potassium tert-Butoxide Promoted Intramolecular Arylation via a Radical Pathway"
Roman SD, et al.
Organic Letters, 13(12), 3242-3245 (2011)
Mizoroki-Heck-type reaction mediated by potassium tert-butoxide
Shirakawa E, et al.
Angewandte Chemie (International ed. in English), 123(20), 4767-4770 (2011)
Synthesis of highly enantiomerically enriched amines by asymmetric transfer hydrogenation of N-(tert-butylsulfinyl) imines
Guijarro D, et al.
Organic Syntheses (2013)
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