161241
1-苯基-1-丙炔
99%
别名:
1-丙烯基苯, 1-炔丙基-1-苯, 1-甲基-2-苯乙炔, 3-苯基-2-丙炔, 甲基苯乙炔, 苯基甲基乙炔, （2-甲基乙炔基）苯
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关于此项目
线性分子式:
C6H5C≡CCH3
化学文摘社编号:
分子量:
116.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
211-607-7
MDL number:
产品名称
1-苯基-1-丙炔, 99%
InChI key
GHUURDQYRGVEHX-UHFFFAOYSA-N
InChI
1S/C9H8/c1-2-6-9-7-4-3-5-8-9/h3-5,7-8H,1H3
SMILES string
CC#Cc1ccccc1
assay
99%
form
liquid
refractive index
n20/D 1.564 (lit.)
bp
185 °C (lit.)
density
0.928 g/mL at 25 °C (lit.)
functional group
phenyl
storage temp.
2-8°C
Quality Level
General description
研究人员已经报道过环戊烯和1-苯基-1-丙炔的共催化反应。研究人员采用程序升温脱附（temperature-programmed desorption）、X射线和双光子发射光谱研究了100K 下铜（111）上1-苯基-1-丙炔的成键性质。1-苯基-1-丙炔是多巴胺-β羟化酶的抑制剂。研究人员已经报道过通过TaCl5和 NbCl5进行1-苯基-1-丙炔的聚合。
1-苯基-1-丙炔可作为各种化学反应的原料，如加成反应和聚合。
1-苯基-1-丙炔可作为各种化学反应的原料，如加成反应和聚合。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Effect of organometallic cocatalysts on the polymerization of 1-phenyl-1-propyne by tantalum pentachloride (TaCl5) and niobium pentachloride (NbCl5).
Masuda T, et al.
Macromolecules, 18(11), 2109-2113 (1985)
Shuhuai Xiang et al.
Journal of the American Chemical Society, 136(16), 5832-5835 (2014-04-12)
Here we report a general method for the measurement of (13)C kinetic isotope effects at natural abundance for reactions that yield two or more products concurrently. We use, as an example, a recently reported Co-catalyzed reaction between cyclopentene and 1-phenyl-1-propyne.
(Arylimido)niobium(V)?Alkylidenes, Nb(CHSiMe3)(NAr)[OC(CF3)3](PMe3)2, That Enable to Proceed Living Metathesis Polymerization of Internal Alkynes
Izawa T and Nomura K
Macromolecules, 53(13), 5266-5279 (2020)
Youngku Sohn et al.
Langmuir : the ACS journal of surfaces and colloids, 23(24), 12185-12191 (2007-10-31)
The bonding properties of 1-phenyl-1-propyne (PP, C6H5CCCH3) on Cu(111) at 100 K have been studied using temperature-programmed desorption (TPD), and X-ray, ultraviolet, and two-photon photoemission spectroscopies (XPS, UPS, and 2PPE). In TPD, there is no evidence for dissociation. Multilayer desorption
G Colombo et al.
The Journal of biological chemistry, 259(24), 15017-15020 (1984-12-25)
The catalytic action of dopamine beta-hydroxylase on 1-phenyl-1-propyne results in concomitant loss of enzyme activity. At pH 5.5 and 25 degrees C, 1-phenyl-1-propyne inactivates dopamine beta-hydroxylase in a mechanism-based fashion. The inactivation rate is first-order, follows saturation kinetics, and is
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