163155
三氯乙酸乙酯
97%
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线性分子式:
Cl3CCO2CH2CH3
化学文摘社编号:
分子量:
191.44
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-212-7
Beilstein/REAXYS Number:
1761567
MDL number:
产品名称
三氯乙酸乙酯, 97%
InChI key
SJMLNDPIJZBEKY-UHFFFAOYSA-N
InChI
1S/C4H5Cl3O2/c1-2-9-3(8)4(5,6)7/h2H2,1H3
SMILES string
CCOC(=O)C(Cl)(Cl)Cl
assay
97%
refractive index
n20/D 1.453 (lit.)
bp
168 °C (lit.)
solubility
alcohol: miscible(lit.)
diethyl ether: miscible(lit.)
water: insoluble(lit.)
density
1.378 g/mL at 25 °C (lit.)
Quality Level
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Application
Ethyl trichloroacetate was used in the synthesis of dichlorocarbon precursor, phenyl(trichloromethyl)methyl.
General description
Ethyl trichloroacetate undergoes atom-transfer radical addition reaction with styrene catalyzed by the Ru-pentamethylcyclopentadienyl complexes.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Mariano A Fernández-Zúmel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(43), 11601-11607 (2009-09-15)
Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atom-transfer radical reactions catalyzed by the complexes [RuCl2Cp*(PPh3)] and [RuClCp*(PPh3)2] (Cp*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing agent magnesium. The reactions of styrene
An Improved Synthesis of Phenyl (trichloro-methyl) mercury from Sodium Methoxide and Ethyl Trichloroacetate.
Schweizer EE and O'Neill GJ.
The Journal of Organic Chemistry, 28(3), 851-852 (1963)
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