Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.5535 (lit.)
bp
127-131 °C/12 mmHg (lit.)
density
1.057 g/mL at 25 °C (lit.)
functional group
ketone
SMILES string
CC1CCc2ccccc2C1=O
InChI
1S/C11H12O/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-5,8H,6-7H2,1H3
InChI key
GANIBVZSZGNMNB-UHFFFAOYSA-N
General description
2-Methyl-1-tetralone undergoes enantioselective hydrogenation catalyzed by 1,4-diamine-ruthenium(II) complexes.
Application
2-Methyl-1-tetralone was used in enantioselective separation of indan, tetralin and benzosuberan derivatives in the presence of chiral additives by capillary electrophoresis.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Takeshi Ohkuma et al.
Organic letters, 6(16), 2681-2683 (2004-07-30)
A combined system of a RuCl(2)(binap)(1,4-diamine) complex and t-C(4)H(9)OK in i-C(3)H(7)OH catalyzes enantioselective hydrogenation of various 1-tetralone derivatives and some methylated 2-cyclohexenones. Hydrogenation of 2-methyl-1-tetralone under dynamic kinetic resolution gives the cis alcohol with high ee. [reaction: see text]
Chiral separations of indan, tetralin and benzosuberan derivatives by capillary electrophoresis.
Gahm K-H, et al.
Journal of Chromatography A, 793(1), 135-143 (1998)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 163228-2.5G | 04061836691240 |