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Merck
CN

16490

溴丙酮酸

≥98.0%

别名:

3-溴-2-氧代丙酸

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关于此项目

线性分子式:
BrCH2COCOOH
化学文摘社编号:
1113-59-3
分子量:
166.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57647568
EC Number:
214-206-5
Beilstein/REAXYS Number:
1746786
MDL number:
MFCD00002587
Assay:
≥98.0%
Form:
(Powder or Crystals or Flakes)

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产品名称

溴丙酮酸, ≥98.0%

InChI key

PRRZDZJYSJLDBS-UHFFFAOYSA-N

InChI

1S/C3H3BrO3/c4-1-2(5)3(6)7/h1H2,(H,6,7)

SMILES string

OC(=O)C(=O)CBr

assay

≥98.0%

form

(Powder or Crystals or Flakes)

mp

77-82 °C

solubility

water: soluble 1 g/10 mL, clear to very slightly hazy, colorless

functional group

bromo
carboxylic acid
ketone

storage temp.

2-8°C

Quality Level

200

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相关类别

Application

将溴丙酮酸用于咪唑并 [1,2- a ] 吡啶-2-羧酸的合成 。

General description

可能含有痕量的二溴丙酮酸
溴丙酮酸是半胱氨酸残基的亲和标记物 †。作为核酸和蛋白质之间的交联剂 。已经研究了溴丙酮酸灭活胰腺核糖核酸酶 A 的动力学 。

Other Notes

半胱氨酸残基的亲和标记；核酸与蛋白质的交联剂

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN8282
BCCK1798
BCCK1409
BCCJ9220
0000210606

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N Nitta et al.
FEBS letters, 166(1), 194-198 (1984-01-23)
Cytosine in nucleic acids can be converted into N4-aminocytosine by treatment with a mixture of hydrazine and bisulfite. The hydrazino group thus formed at position 4 of the pyrimidine ring can be linked to a sulhydryl group in proteins by
Ananda Herath et al.
Organic letters, 12(3), 412-415 (2009-12-30)
The first continuous flow synthesis of imidazo[1,2-a]pyridine-2-carboxylic acids directly from 2-aminopyridines and bromopyruvic acid has been developed, representing a significant advance over the corresponding in-flask method. The process was applied to the multistep synthesis of imidazo[1,2-a]pyridine-2-carboxamides, including a Mur ligase
M H Wang et al.
The Biochemical journal, 320 ( Pt 1), 187-192 (1996-11-15)
The kinetic theory of substrate reaction during the modification of enzyme activity [Duggleby (1986) J. Theor. Biol. 123, 67-80; Wang and Tsou (1990) J. Theor. Biol. 142, 531-549] has been applied to a study of the inactivation kinetics of ribonuclease
P M Alliel et al.
European journal of biochemistry, 105(2), 343-351 (1980-04-01)
We have reported in a previous communication a kinetic study showing bromopyruvate to behave as an active-site-directed reagent for flavocytochrome b2. It is shown here that inactivation is accompanied by incorporation of 3 mol reagent/subunit of oxidized intact enzyme and
Alvaro Marín-Hernández et al.
Archives of toxicology, 86(5), 753-766 (2012-02-22)
The copper-based drug Casiopeina II-gly (CasII-gly) shows potent antineoplastic effect and diminishes mitochondrial metabolism on several human and rodent malignant tumors. To elucidate whether CasII-gly also affects glycolysis, (a) the flux through the complete pathway and the initial segment and
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