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165263

2-乙基乙酰乙酸乙酯

Name: 2-乙基乙酰乙酸乙酯
Brand: ALDRICH

90%

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关于此项目

线性分子式:

CH₃COCH(C₂H₅)COOC₂H₅

化学文摘社编号:

607-97-6

分子量:

158.19

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850132

EC Number:

210-151-6

Beilstein/REAXYS Number:

636286

MDL number:

MFCD00039898

Assay:

90%

Form:

liquid

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属性

assay

90%

form

liquid

refractive index

n20/D 1.421 (lit.)

bp

87-189 °C/743 mmHg (lit.)

density

0.981 g/mL at 25 °C (lit.)

functional group

ester, ketone

SMILES string

CCOC(=O)C(CC)C(C)=O

InChI

1S/C8H14O3/c1-4-7(6(3)9)8(10)11-5-2/h7H,4-5H2,1-3H3

InChI key

OKANYBNORCUPKZ-UHFFFAOYSA-N

说明

Application

Ethyl 2-ethylacetoacetate was used in the synthesis of 2-alkylidenetetrahydrofurans, diphenyllead(IV) thiosemicarbazonates and pyrazolonates. It was used as starting reagent in the synthesis of 2-ethylfumaric acid.

存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

156.2 °F - closed cup

flash_point_c

69 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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Diphenyllead (IV) thiosemicarbazonates and pyrazolonates: Synthesis and characterization.

Casas JS, et al.

Polyhedron, 28(5), 1029-1039 (2009)

Characterization of a thermostable methylaspartate ammonia lyase from Carboxydothermus hydrogenoformans.

Hans Raj et al.

Applied microbiology and biotechnology, 94(2), 385-397 (2011-10-19)

Methylaspartate ammonia lyase (MAL; EC 4.3.1.2) catalyzes the reversible addition of ammonia to mesaconate to give (2S,3S)-3-methylaspartate and (2S,3R)-3-methylaspartate as products. MAL is of considerable biocatalytic interest because of its potential use for the asymmetric synthesis of substituted aspartic acids

Efficient synthesis of functionalized furans and benzofurans based on a '[3+ 2] cyclization/oxidation'strategy.

Bellur E, et al.

Tetrahedron Letters, 46(13), 2185-2187 (2005)

全球贸易项目编号

货号	GTIN
165263-25G	04061838748621