16571
(+)-3-溴樟脑
purum, ≥97.0% (sum of enantiomers, GC)
别名:
内型-(1R)-3-溴-1,7,7-三甲基二环[2.2.1]庚烷-2-酮
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关于此项目
经验公式（希尔记法）:
C10H15BrO
化学文摘社编号:
分子量:
231.13
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-652-1
Beilstein/REAXYS Number:
3197237
MDL number:
产品名称
(+)-3-溴樟脑, purum, ≥97.0% (sum of enantiomers, GC)
InChI key
NJQADTYRAYFBJN-FWWHASMVSA-N
InChI
1S/C10H15BrO/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6-7H,4-5H2,1-3H3/t6-,7+,10+/m1/s1
SMILES string
[H][C@@]12CC[C@@](C)(C(=O)[C@H]1Br)C2(C)C
grade
purum
assay
≥97.0% (sum of enantiomers, GC)
form
solid
optical activity
[α]20/D +136±3°, c = 1% in ethanol
mp
75-77 °C
functional group
bromo
ketone
Quality Level
Other Notes
作为手性结构单元；用于脱溴-硅烷化和-膦羧化反应
Application
- Insights into the mechanisms of within-species variation in sensitivity to chemicals: A case study using daphnids exposed to CMIT/MIT biocide.: This study investigates the differential sensitivity of daphnids to 2-Methyl-4-isothiazolin-3-one, highlighting the biochemical mechanisms underlying these variations. The findings provide crucial insights for environmental safety assessments (Kim et al., 2023).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
P. Sampson et al.
The Journal of Organic Chemistry, 51, 4342-4342 (1986)
R.V. Stevens et al.
Tetrahedron, 41, 93-93 (1985)
J.H. Hutchinson et al.
Canadian Journal of Chemistry, 65, 1-1 (1987)
Camphor: a chiral starting material in natural product synthesis.
T Money
Natural product reports, 2(3), 253-289 (1985-06-01)
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