167169
3-溴-1-丙醇
97%
别名:
三甲烯溴醇
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关于此项目
线性分子式:
Br(CH2)3OH
化学文摘社编号:
分子量:
138.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-986-6
Beilstein/REAXYS Number:
969160
MDL number:
产品名称
3-溴-1-丙醇, 97%
InChI key
RQFUZUMFPRMVDX-UHFFFAOYSA-N
InChI
1S/C3H7BrO/c4-2-1-3-5/h5H,1-3H2
SMILES string
OCCCBr
assay
97%
form
liquid
refractive index
n20/D 1.488 (lit.)
bp
62 °C/5 mmHg (lit.)
density
1.537 g/mL at 25 °C (lit.)
functional group
bromo
hydroxyl
storage temp.
2-8°C
Quality Level
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Application
3-溴-1-丙醇被用于合成对荧光卤素敏感的喹啉类染料和熔融盐聚合物 。它被用于通过季铵氨基酸环化合成手性、季铵脯氨酸 。
最近用作斯文氧化法合成绿色试剂的接枝剂
General description
在胶束介质和阳离子或非离子表面活性剂微乳液中，研究了 3-溴-1-丙醇、苯酚和一系列取代苯酚的反应。
3-溴-1-丙醇是一种亲电子试剂，可在亲核取代反应和氧化还原聚合反应中作为底物。
3-溴-1-丙醇是一种亲电子试剂，可在亲核取代反应和氧化还原聚合反应中作为底物。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Fredrik Currie
Journal of colloid and interface science, 277(1), 230-234 (2004-07-28)
The reaction between 3-bromo-1-propanol and phenol and a series of phenols carrying substituents in 4-position was studied in micellar media and in microemulsions based on either a cationic or a nonionic surfactant. The reactivity and the yield were evaluated and
Takeo Kawabata et al.
Journal of the American Chemical Society, 128(48), 15394-15395 (2006-11-30)
An enantiodivergent asymmetric cyclization of N-Boc-N-omega-bromoalkyl-alpha-amino acid derivatives has been developed. With potassium amide bases in DMF, cyclization proceeds with retention of configuration, while inversion of configuration was observed with lithium amide bases in THF. Chirality of the parent amino
Wei Song et al.
Molecules (Basel, Switzerland), 25(17) (2020-08-23)
Azobenzene (AB) units were successfully introduced into poly(1,6-heptadiyne)s in order to ensure smooth synthesis of double- and single-stranded poly(1,6-heptadiyne)s (P1 and P2) and simultaneously realize the self-assembly by Grubbs-III catalyst-mediated metathesis cyclopolymerization (CP) of AB-functionalized bis(1,6-heptadiyne) and 1,6-heptadiyne monomers (M1
Use of self-assembled surfactant systems as media for a substitution reaction
Fredrik and Currie
Journal of Colloid and Interface Science, 277, 230-234 (2004)
Synthesis and characterization of various block copolymers using PMMA-Br macroinitiator
Melahat and Goktacs et al.
Chemical Papers, 73, 2329-2339 (2019)
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