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Merck
CN

171441

三氟碘甲烷

99%

别名:

三氟甲基碘, 全氟甲基碘, 碘代三氟甲烷

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关于此项目

经验公式(希尔记法):
CF3I
化学文摘社编号:
分子量:
195.91
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
219-014-5
Beilstein/REAXYS Number:
1732740
MDL number:
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产品名称

三氟碘甲烷, 99%

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

InChI

1S/CF3I/c2-1(3,4)5

SMILES string

FC(F)(F)I

assay

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

functional group

fluoro
iodo

Quality Level

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Application

用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。

Packaging

以Sure/Pac 气瓶供货,并具有配备 1/4" NPTF出口外螺纹的青铜针阀。使用样品筒之前,确保关闭阀门,然后拆下密封出气阀的镀锌钢六角帽。

与以下装置兼容:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

signalword

Warning

Hazard Classifications

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

存储类别

2A - Gases

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Andreas Vargas Jentzsch et al.
Nature communications, 3, 905-905 (2012-06-21)
In biology and chemistry, the transport of anions across lipid bilayer membranes is usually achieved by sophisticated supramolecular architectures. Significant size reduction of transporters is hampered by the intrinsically hydrophilic nature of typical anion-binding functionalities, hydrogen-bond donors or cations. To
Yingda Ye et al.
Journal of the American Chemical Society, 134(22), 9034-9037 (2012-05-26)
This communication describes the development of a mild method for the cross-coupling of arylboronic acids with CF(3)I via the merger of photoredox and Cu catalysis. This method has been applied to the trifluoromethylation of electronically diverse aromatic and heteroaromatic substrates
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced

商品

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

在2001年,佛罗里达大学的William Dolbier,Jr.教授报告了一种亲核三氟甲基化的方法,该方法基于在强力双电子还原剂四(二甲基氨基)乙烯(TDAE)存在下使用CF3I生成三氟甲基阴离子。

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