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Merck
CN

182605

聚(9-乙烯基咔唑)

average Mw ~1,100,000, powder

别名:

PVK

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关于此项目

化学文摘社编号:
25067-59-8
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
MFCD00134336

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SMILES string

[n]1(c2c(c3c1cccc3)cccc2)C=C

InChI

1S/C14H11N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h2-10H,1H2

InChI key

KKFHAJHLJHVUDM-UHFFFAOYSA-N

form

powder

mol wt

average Mw ~1,100,000

refractive index

n20/D 1.683

transition temp

Tg 220 °C

density

1.2 g/mL at 25 °C (lit.)

orbital energy

HOMO 5.8 eV , LUMO 2.2 eV 

OLED device performance

ITO/PEDOT:PSS/PVK/PFO:Ir(btpy)3 (5 wt%)/Ca

  • Color: red
  • Max. Luminance: 726.5 Cd/m2
  • Max. EQE: 2.32 %
, ITO/PEDOT:PSS/PVK:FIr6 (10 wt%)/TPBI/CsF:Al
  • Color: blue
  • Max. Luminance: 13800 Cd/m2
  • Max. EQE: 1.98 %
  • Turn-On Voltage: 5.5 V
, ITO/PEDOT:PSS/PVK:Ir(mppy)2 (6 wt%)/Bphen/LiF:Al
  • Color: green
  • Max. Luminance: 10000 Cd/m2
  • Max. EQE: 1.1 %
  • Turn-On Voltage: 3.8 V

Quality Level

100

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相关类别

Application

PVK：氧化石墨烯复合材料可作为复合薄膜涂覆于二氧化硅基板上，用于制造有机场效应晶体管(OFET)。它可与碳纳米球(CNS)形成纳米复合薄膜，用于超级电容器和传感器类应用。

General description

聚(9-乙烯基咔唑)(PVK)是一种导电聚合物，主要用作低驱动电压的高效空穴传输介质。它还可用作空穴注入的阳极，共掺杂有机染料后可用作有效的电荷转移栅极。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCJ1229
MKCF0613
MKBW1965V
MKBT9870V
MKBQ2008V

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Poly (9-vinylcarbazole)-graphene oxide composite field-effect transistors with enhanced mobility
Aleshin AN, et al.
Organic Electronics, 16(3), 186-194 (2015)
Thermally Cross-Linkable Hole-Transporting Materials for Improving Hole Injection in Multilayer Blue-Emitting Phosphorescent Polymer Light-Emitting Diodes
Liu, M. S.; et al.
Marcromolecules, 41, 9570-9580 (2008)
Meng-xin Zhang et al.
Guang pu xue yu guang pu fen xi = Guang pu, 25(6), 836-839 (2005-10-06)
Rare earth complex TbY(m-MBA)6 (phen)2.2H20 have been synthesized, which were used as emitting materials in electroluminescence. Single-layer devices and bilayer devices with Alq as electron transmission layer have been fabricated. The electroluminescent properties of the devices were studied. The electroluminescent
Takuro Midorikawa et al.
Journal of nanoscience and nanotechnology, 7(4-5), 1419-1426 (2007-04-25)
Photoinduced electron-transfer and hole-migration processes for newly prepared copolymers of C60 and N-vinylcarbazole (VCz) with the several compositions have been investigated using time-resolved fluorescence and absorption methods. Shortening of fluorescence lifetime of the C60 moiety in PVCz-C60 was observed, suggesting
Blue electroluminescent diodes utilizing blends of poly (p-phenylphenylene vinylene) in poly (9-vinylcarbazole)
Zhang C, et al.
Synthetic Metals, 62(1), 35-40 (1994)
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发光聚合物

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