183075
1-甲基靛红
97%
别名:
N-Methylindoline-2,3-dione, NSC 42449
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关于此项目
经验公式（希尔记法）:
C9H7NO2
化学文摘社编号:
分子量:
161.16
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
97%
表单
solid
mp
130-133 °C (lit.)
官能团
ketone
SMILES字符串
CN1C(=O)C(=O)c2ccccc12
InChI
1S/C9H7NO2/c1-10-7-5-3-2-4-6(7)8(11)9(10)12/h2-5H,1H3
InChI key
VCYBVWFTGAZHGH-UHFFFAOYSA-N
基因信息
human ... CASP3(836)
一般描述
The interaction between 1-methylisatin and human adult haemoglobin was studied using the circular dichroism (CD) spectroscopic, anisotropy and FTIR investigations.
应用
- Reactant for stereoselective preparation of spirobicyclic and bis-spirotricyclic pyrazolidinones
- Reactant for regioselective preparation of spirocyclic oxindole-butenolides
- Reactant for synthesis of spiro-oxindoles
- Reactant for preparation of unsymmetrical oxindoles
- Reactant for stereoselective preparation of hydroxyloxindoles via Morita-Baylis-Hillman reaction
- Reactant for preparation of pyridinecarboxylic acid [(oxo)indolylidene)hydrazide derivatives (Schiff base hydrazides) as antibacterial agents
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
María C Rodríguez-Argüelles et al.
Journal of inorganic biochemistry, 101(1), 138-147 (2006-10-31)
Cobalt(II), nickel(II), copper(II) and zinc(II) complexes of 2-thiophenecarbonyl and isonicotinoyl hydrazones of 3-(N-methyl)isatin (HL(1) and HL(2), respectively) were synthesized and characterized, being the crystal structures of HL(1), HL(2) and [Ni(L(1))(2)].2CHCl(3) elucidated by X-ray diffraction techniques. The in vitro antimicrobial activity
Verena Schulz et al.
Organic letters, 9(9), 1745-1748 (2007-03-31)
[reaction: see text] The in situ preparation of a sulfonium ylide reagent achieved the highly diastereoselective epoxidation of isatins, so that a new and straightforward access to biologically significant spiro-epoxyoxindoles is provided. The first investigations of an asymmetric version are
M S Mirrlees et al.
Drug design and discovery, 11(3), 223-230 (1994-04-01)
Alkaline hydrolysis of the title isatin 4 in unbuffered solution obeys a rate law such that kobs varies; is directly proportional to [OH-]2 at pH 10 changes smoothly to kobs varies; is directly proportional to [OG-] by pH 13. As
L Sebastian et al.
Letters in applied microbiology, 55(3), 234-239 (2012-06-29)
To investigate the drug to drug interaction of N-methylisatin-β-thiosemicarbazone (MIBT) derivative (SCH16) with ribavirin, mycophenolic acid and pentoxifylline against Japanese encephalitis virus in vitro. Our earlier studies have reported significant antiviral activity of these compounds against Japanese encephalitis virus in
Jaime F Martínez Suárez et al.
The Journal of organic chemistry, 84(11), 6879-6885 (2019-05-16)
Isatin in a solution of dry N,N-dimethylformamide/NaClO4 is electroreduced in the presence of CH3I. N-methylisatin (NMI) is obtained in quantitative molar yield and high current efficiency by controlled potential electrolysis (CPE). NMI and N-methylisatoic anhydride are the reaction products when
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