187879
2,5-二甲氧基苯甲醇
99%
别名:
(2,5-Dimethoxyphenyl)methanol, 1-(Hydroxymethyl)-2,5-dimethoxybenzene, 2,5-Dimethoxybenzenemethanol
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关于此项目
线性分子式:
(CH3O)2C6H3CH2OH
化学文摘社编号:
分子量:
168.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-562-0
Beilstein/REAXYS Number:
1947607
MDL number:
产品名称
2,5-二甲氧基苯甲醇, 99%
InChI key
WGQMUABRZGUAOS-UHFFFAOYSA-N
InChI
1S/C9H12O3/c1-11-8-3-4-9(12-2)7(5-8)6-10/h3-5,10H,6H2,1-2H3
SMILES string
COc1ccc(OC)c(CO)c1
assay
99%
refractive index
n20/D 1.547 (lit.)
bp
122-125 °C/1 mmHg (lit.)
density
1.173 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
2,5-Dimethoxybenzyl alcohol was used as starting reagent in the synthesis of [(S)S]-3,6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde. It was used in the synthesis of daunornycinone. It was also used in the preparation of pillar[n]arenes (n = 5 or 6) via cyclooligomerization reaction with an appropriate Lewis acid catalyst.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
An exceptional 5-endo-trig reversal; a convergent synthesis of daunomycinone.
Keay BA and Rodrigo R.
Canadian Journal of Chemistry, 61(3), 637-639 (1983)
Diastereodivergent additions of aluminum and magnesium reagents to [(S)S]-3, 6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde.
Almori'n A, et al.
Tetrahedron Letters, 44(30), 5597-5600 (2003)
Preparation of Pillar [n] arenes by Cyclooligomerization of 2, 5-Dialkoxybenzyl Alcohols or 2, 5-Dialkoxybenzyl Bromides.
Ma Y, et al.
European Journal of Organic Chemistry, 2011(27), 5331-5335 (2011)
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