189138
四丁基溴化膦
98%, solid
别名:
Tetra-n-butylphosphonium bromide
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4P(Br)
化学文摘社编号:
分子量:
339.33
Beilstein:
4160474
EC 号:
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
产品名称
四丁基溴化膦, 98%
质量水平
方案
98%
表单
solid
环保替代产品特性
Catalysis
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mp
100-103 °C (lit.)
环保替代产品分类
, Aligned
SMILES字符串
[Br-].CCCC[P+](CCCC)(CCCC)CCCC
InChI
1S/C16H36P.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChI key
RKHXQBLJXBGEKF-UHFFFAOYSA-M
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一般描述
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处以获取更多信息。
应用
四丁基溴化膦是一种季盐，可用作：
- 作为分散钌催化剂的介质，用于通过钌熔融催化（ ruthenium melt catalysis）由合成气合成乙二醇。
- 作为二氧化硅或氧化铝上负载的催化剂，用于烷基氯的卤素交换反应合成烷基溴。
- 与不同比例的1,3-二甲基脲混合以合成用于捕获NO气体各种离子液体。
- 作为氢键受体与氢键供体乙酰丙酸一起用于制备深共晶溶剂，从而分离出甲苯/正己烷混合物中的甲苯。
- 制备离子型半笼型水合物，
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Repr. 2 - Skin Sens. 1B
储存分类代码
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
闪点(°F)
554.0 °F - closed cup
闪点(°C)
290 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Fuel Processing Technology, 135(1), 99-104 (2015)
Thermodynamic properties of ionic semiclathrate hydrate formed with tetrabutylphosphonium bromide
Suginaka T
Fluid Phase Equilibria, 317(1), 25-28 (2012)
1, 3-Dimethylurea tetrabutylphosphonium bromide ionic liquids for NO efficient and reversible capture
Jiang B, et al.
Energy and Fuels, 30(1), 735-739 (2016)
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Chemphyschem : a European journal of chemical physics and physical chemistry, 19(13), 1674-1682 (2018-04-25)
The mechanism of CO2 absorption by a formate ionic liquid, [P4444 ]HCOO, was studied by Raman spectroscopy. The band area for the symmetric CO2 stretching of the formate anion linearly decreases with the CO2 loading. From the slope of the
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