208302
硫氰酸铅(II)
99.5% trace metals basis
别名:
Lead sulfocyanide, 硫氰化铅(II), 硫氰酸铅
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关于此项目
线性分子式:
Pb(SCN)2
化学文摘社编号:
分子量:
323.36
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-774-6
Beilstein/REAXYS Number:
3687984
MDL number:
产品名称
硫氰酸铅(II), 99.5% trace metals basis
InChI key
VRNINGUKUJWZTH-UHFFFAOYSA-L
InChI
1S/2CHNS.Pb/c2*2-1-3;/h2*3H;/q;;+2/p-2
SMILES string
N#CS[PbH2]SC#N
assay
99.5% trace metals basis
form
powder
mp
190 °C (dec.) (lit.)
solubility
cold water: soluble 200 part(lit.)
water: soluble 50 part (boiling)(lit.)
density
3.82 g/mL at 25 °C (lit.)
Quality Level
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Application
硫氰酸铅(II)可用于：
- 与席夫碱套索冠醚——N,N′-双（3-（水杨醛亚胺）苄基）-4,13-二氮杂-18-冠-6形成络合物。
- 研究大孔介孔硅材料上含两个丹酰荧光团的杯芳烃之络合和荧光性质。
- 在（二氯碘）苯存在下炔烃的1,2-二硫氰化反应中用作试剂。
- 作为前体合成钙钛矿薄膜，以用于太阳能电池。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
(Dichloroiodo) benzene and lead (II) thiocyanate as an efficient reagent combination for stereoselective 1, 2-dithiocyanation of alkynes
Prakash O, et al.
Tetrahedron Letters, 42(4), 553-555 (2001)
A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water
M'etivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2965-2973 (2005)
Lead (II) thiocyanate complexes with bibracchial lariat ethers: an X-ray and DFT study
Platas-Iglesias C, et al.
Inorganic Chemistry, 44(7), 2224-2233 (2005)
A mesoporous silica functionalized by a covalently bound calixarene-based fluoroionophore for selective optical sensing of mercury (II) in water.
Metivier R, et al.
Journal of Materials Chemistry, 15(27-28), 2695-2673 (2005)
Carlos Platas-Iglesias et al.
Inorganic chemistry, 44(7), 2224-2233 (2005-03-29)
Compounds of formula [Pb(L2)(NCS)2] (1) and [Pb(L4)(SCN)2] (2) (where L2 is the lariat crown ether N,N'-bis(3-aminobenzyl)-4,13-diaza-18-crown-6 and L4 is the Schiff-base lariat crown ether N,N'-bis(3-(salicylaldimino)benzyl)-4,13-diaza-18-crown-6) were isolated and structurally characterized by X-ray diffraction analyses. The X-ray crystal structures of both
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