208795
甲基硫代磺酸甲酯
97%
别名:
S-甲基硫代甲基砜, MMTS
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.513 (lit.)
沸点
69-71 °C/0.4 mmHg (lit.)
溶解性
DMF: soluble 1:1
chloroform: soluble 200 ul per mL, clear, faintly yellow-green
water: soluble 1:5
密度
1.337 g/mL at 25 °C (lit.)
官能团
disulfide
SMILES字符串
CSS(C)(=O)=O
InChI
1S/C2H6O2S2/c1-5-6(2,3)4/h1-2H3
InChI key
XYONNSVDNIRXKZ-UHFFFAOYSA-N
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一般描述
S-甲基硫代磺酸甲酯是用于合成硫醇和硫酯的试剂。用作制备聚合物网络的交联剂。 S-甲基硫代磺酸甲酯（MMTS）与二棕榈酰磷脂酰胆碱（DPPC）双层的相互作用已经通过FTIR和表面增强拉曼光谱进行研究。
应用
S-甲基硫代磺酸甲酯被用作β-酮亚砜、亚甲基化合物、丙二酸半酯 和芳基格氏试剂的亚磺酰化试剂。它还被用作捕获天然硫醇-二硫化物形式的蛋白质的试剂。
储存分类代码
10 - Combustible liquids
WGK
WGK 2
闪点(°F)
188.6 °F - closed cup
闪点(°C)
87 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
P Mampuys, et al.
Angewandte Chemie (International Edition in English), 126, 13063-13068 (2014)
Synthetic Communications, 22, 1359-1359 (1992)
The Journal of Organic Chemistry, 58, 6132-6132 (1993)
Sustainable Three-Component Synthesis of Isothioureas from Isocyanides, Thiosulfonates, and Amines
P Mampuys, et al.
Angewandte Chemie (International Edition in English), 126 (2014)
María E Defonsi Lestard et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 479-489 (2012-07-27)
The present study is a first step towards the investigation of S-methyl methanethiosulfonate (MMTS) interaction with membrane model systems like liposomes. In this paper, the interaction of MMTS with dipalmitoylphosphatidylcholine (DPPC) bilayers was studied by FTIR and SERS spectroscopy. Lysolipid
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